Synthesis of reaction‐adapted zeolites as methanol-to-olefins catalysts with mimics of reaction intermediates as organic structure‐directing agents

C Li, C Paris, J Martínez-Triguero, M Boronat… - Nature Catalysis, 2018 - nature.com
Catalysis with enzymes and zeolites have in common the presence of well-defined single
active sites and pockets/cavities where the reaction transition states can be stabilized by …

Impact of Zeolite Framework Composition and Flexibility on Methanol‐To‐Olefins Selectivity: Confinement or Diffusion?

P Ferri, C Li, R Millán, J Martínez‐Triguero… - Angewandte …, 2020 - Wiley Online Library
The methanol‐to‐olefins reaction catalyzed by small‐pore cage‐based acid zeolites and
zeotypes produces a mixture of short chain olefins, whose selectivity to ethene, propene and …

[引用][C] Insights into the mechanism of methanol‐to‐olefin conversion at zeolites with systematically selected framework structures

ZM Cui, Q Liu, WG Song, LJ Wan - Angewandte Chemie, 2006 - Wiley Online Library
zeolites were selected on the basis of the maximum diameter of a sphere that could be
included in the framework.[22] ZSM-11 and ZSM-22 have similar pore openings; however …

Effect of cage size on the selective conversion of methanol to light olefins

Y Bhawe, M Moliner-Marin, JD Lunn, Y Liu… - Acs …, 2012 - ACS Publications
Zeolites that contain eight-membered ring pores but different cavity geometries (LEV, CHA,
and AFX structure types) are synthesized at similar Si/Al ratios and crystal sizes. These …

Rational design of zeolite catalysts

JD Rimer - Nature Catalysis, 2018 - nature.com
The identification of organic structure-directing agents capable of tailoring the
physicochemical properties of microporous materials has remained a challenge. Now, a …

Conversion of methanol to alkenes over medium-and large-pore acidic zeolites: Steric manipulation of the reaction intermediates governs the ethene/propene product …

S Svelle, U Olsbye, F Joensen… - The Journal of Physical …, 2007 - ACS Publications
Methanol conversion over H-beta and H-ZSM-5 zeolite catalysts is compared at identical
reaction conditions (temperature= 350° C, WHSV= 7.0 gg-1 h-1), and it is found that H-ZSM …

Structure–performance descriptors and the role of Lewis acidity in the methanol-to-propylene process

I Yarulina, K De Wispelaere, S Bailleul, J Goetze… - Nature …, 2018 - nature.com
The combination of well-defined acid sites, shape-selective properties and outstanding
stability places zeolites among the most practically relevant heterogeneous catalysts. The …

Chemical and structural parameter connecting cavity architecture, confined hydrocarbon pool species, and MTO product selectivity in small-pore cage-based zeolites

P Ferri, C Li, C Paris, A Vidal-Moya, M Moliner… - ACS …, 2019 - ACS Publications
The catalysts used in the methanol-to-olefins (MTO) reaction are considered dual systems
comprising an inorganic zeolite framework and organic compounds hosted inside that act as …

Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity

U Olsbye, S Svelle, M Bjørgen, P Beato… - Angewandte Chemie …, 2012 - Wiley Online Library
Liquid hydrocarbon fuels play an essential part in the global energy chain, owing to their
high energy density and easy transportability. Olefins play a similar role in the production of …

New trends in tailoring active sites in zeolite-based catalysts

M Shamzhy, M Opanasenko, P Concepción… - Chemical Society …, 2019 - pubs.rsc.org
This review addresses the recent developments and trends in tailoring the nature and local
properties of active sites in zeolite-based catalysts, with a special focus on novel extra-large …