Simultaneous characterization of solid acidity and basicity of metal oxide catalysts via the solid-state NMR technique

Y Fu, L Zhang, B Yue, X Chen, H He - The Journal of Physical …, 2018 - ACS Publications
A novel characterization method for simultaneous determination of acidity and basicity of
metal oxide catalysts has been developed by using the solid-state NMR technique. Three …

Acidity characterization of heterogeneous catalysts by solid-state NMR spectroscopy using probe molecules

A Zheng, SB Liu, F Deng - Solid State Nuclear Magnetic Resonance, 2013 - Elsevier
Abstract Characterization of the surface acidic properties of solid acid catalysts is a key issue
in heterogeneous catalysis. Important acid features of solid acids, such as their type …

Progress in development and application of solid-state NMR for solid acid catalysis

A Zheng, SJ HUANG, W Qiang, H Zhang… - Chinese Journal of …, 2013 - Elsevier
Solid acid catalysts have been widely used in petrochemical industry and their catalytic
activities are normally dictated by their acidities. Unlike conventional acidity characterization …

Solid-state NMR characterization of the structure and catalytic reaction mechanism of solid acid catalysts

SH LI, J LI, AM ZHENG, F DENG - Acta Physico-Chimica Sinica, 2017 - ingentaconnect.com
Solid acid catalysts have been widely used in advanced petrochemical processes because
of their environmental friendliness, high product selectivity, and easy product separation …

An NMR scale for measuring the base strength of solid catalysts with pyrrole probe: a combined solid-state NMR experiment and theoretical calculation study

X Yi, G Li, L Huang, Y Chu, Z Liu, H Xia… - The Journal of …, 2017 - ACS Publications
Pyrrole has been employed as an NMR probe molecule to determine the base strength of
solid catalytic materials; however, the quantitative correlation between the 1H chemical shift …

[HTML][HTML] 109 Ag NMR chemical shift as a descriptor for Brønsted acidity from molecules to materials

C Hansen, SR Docherty, W Cao, AV Yakimov… - Chemical …, 2024 - pubs.rsc.org
Molecular-level understanding of the acid/base properties of heterogeneous catalysts
requires the development of selective spectroscopic probes to establish structure–activity …

Solid-state NMR characterization of acid properties of zeolites and solid acid catalysts

J Xu, Q Wang, S Li, F Deng, J Xu, Q Wang, S Li… - Solid-State NMR in …, 2019 - Springer
This chapter introduces the application of solid-state NMR to investigate the acid features of
solid acid catalysts, which have been widely used in advanced petrochemical processes …

Comprehensive IR study on acid/base properties of metal oxides

M Tamura, K Shimizu, A Satsuma - Applied Catalysis A: General, 2012 - Elsevier
Acid/base properties (type, strength, number) of a wide range of metal oxides were studied
by IR (infra-red) spectroscopy. Ammonia, pyridine and CD3CN were used as probe …

Surface fingerprinting of faceted metal oxides and porous zeolite catalysts by probe-assisted solid-state NMR approaches

X Yi, YK Peng, W Chen, Z Liu… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Acid catalysis in heterogeneous systems such as metal oxides and porous
zeolites has been widely involved in various catalytic processes for chemical and …

Qualitative and quantitative analysis of acid properties for solid acids by solid-state nuclear magnetic resonance spectroscopy

W Yang, Z Wang, J Huang, Y Jiang - The Journal of Physical …, 2021 - ACS Publications
Silica–alumina-based solid acid is one of the most popular heterogeneous catalysts utilized
in the petrochemical process and biorefining. The acid density, strength, and accessibility of …