This article focuses on the development of practical approaches to the in situ generation of
anhydrous fluoride salts for applications in nucleophilic aromatic substitution (SNAr) …

Nucleophilic aromatic fluorination (SNAr) is among the most common methods for the
formation of C (sp2)–F bonds. Despite many recent advances, a long-standing limitation of …

This paper describes the room-temperature SNAr fluorination of aryl halides and nitroarenes
using anhydrous tetramethylammonium fluoride (NMe4F). This reagent effectively converts …

Conspectus The identification of reliable, general, and high yielding methods for the
formation of C (sp2)–fluorine bonds remains a major challenge for synthetic organic …

This paper describes a detailed study of the deoxyfluorination of aryl fluorosulfonates with
tetramethylammonium fluoride (NMe4F) and ultimately identifies other sulfonate …

A “one-pot” tandem substitution/Krapcho reaction is reported for the facile synthesis of α-
fluorinated esters and sulfones, which utilizes the byproduct salt formed in the substitution …

The reaction of acid fluorides with N-heterocyclic carbenes (NHCs) produces anhydrous
acyl azolium fluorides. With appropriate selection of acid fluoride and NHC, these salts can …

SNAr Reactions of Nitro-(pentafluorosulfanyl)benzenes To Generate SF5 Aryl Ethers and
Sulfides | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic …

Here we report an efficient access to high‐value N‐polyfluoroalkyl anilines, primary
polyfluoroalkylamines and N, N‐bis (polyfluoroalkyl) amines, via N‐polyfluoroalkylation of …

Herein, we report a new method for the one-pot syntheses of sulfonyl fluorides. Addition of
an alkyl, aryl, or heteroaryl Grignard to a solution of sulfuryl fluoride at ambient temperature …