Water Solubility Trends in Ionic Liquids: The Quantitative Structure–Property Relationship Model versus Molecular Dynamics

CES Bernardes, K Klimenko… - The Journal of …, 2021 - ACS Publications
The knowledge of water solubility in ionic liquids (ILs) is an important property with an
impact on the design of many physical and chemical processes, like the purification of …

Mutual solubilities of water and hydrophobic ionic liquids

MG Freire, CMSS Neves, PJ Carvalho… - The Journal of …, 2007 - ACS Publications
The ionic nature of ionic liquids (ILs) results in a unique combination of intrinsic properties
that produces increasing interest in the research of these fluids as environmentally friendly …

Solubility of non-aromatic ionic liquids in water and correlation using a QSPR approach

MG Freire, CMSS Neves, SPM Ventura, MJ Pratas… - Fluid phase …, 2010 - Elsevier
The solubility of ionic liquids (ILs) in water is of significant relevance for both process design
and evaluation of their environmental impact. In this work, the solubilities of the non-aromatic …

What determines the miscibility of ionic liquids with water? Identification of the underlying factors to enable a straightforward prediction

M Klähn, C Stüber, A Seduraman… - The Journal of Physical …, 2010 - ACS Publications
Whether an ionic liquid (IL) is water-miscible or immiscible depends on the particular ions
that constitute it. We propose an explanation, based on molecular simulations, how ions …

Impact of the cation symmetry on the mutual solubilities between water and imidazolium-based ionic liquids

MAR Martins, CMSS Neves, KA Kurnia, A Luís… - Fluid Phase …, 2014 - Elsevier
Aiming at the evaluation of the impact of the ionic liquids (ILs) cation symmetry on their
phase behaviour, in this work, novel mutual solubilities with water of the symmetric series of …

Ammonium ionic liquid solubilities in water and micellar formation

R Keyes, P Scovazzo - The Journal of Physical Chemistry B, 2017 - ACS Publications
A number of proposed applications for ionic liquids (ILs) involve IL/water interfaces, such as
chemical separations or drug delivery. Therefore, an understanding of the solubility and …

Analysis of the isomerism effect on the mutual solubilities of bis (trifluoromethylsulfonyl) imide-based ionic liquids with water

MAR Martins, CMSS Neves, KA Kurnia, LM Santos… - Fluid Phase …, 2014 - Elsevier
The knowledge of the liquid–liquid equilibria (LLE) between ionic liquids (ILs) and water is
of utmost importance for environmental monitoring, process design and optimization …

An overview of the mutual solubilities of water–imidazolium-based ionic liquids systems

MG Freire, LM Santos, AM Fernandes… - Fluid Phase …, 2007 - Elsevier
Ionic liquids (ILs) are a novel class of chemical compounds with interesting properties that
are driving a lot of research in several fields. For ionic liquids to be effectively used as …

Comprehensive study on the impact of the cation alkyl side chain length on the solubility of water in ionic liquids

KA Kurnia, CMSS Neves, MG Freire, LM Santos… - Journal of molecular …, 2015 - Elsevier
A comprehensive study on the phase behaviour of two sets of ionic liquids (ILs) and their
interactions with water is here presented through combining experimental and theoretical …

Ion specific effects on the mutual solubilities of water and hydrophobic ionic liquids

MG Freire, PJ Carvalho, AMS Silva… - The Journal of …, 2009 - ACS Publications
Ion specific effects on the mutual solubilities between hydrophobic ionic liquids (ILs) and
water are complex and not fully understood. The aim of this work is to obtain further …