Intercepting hydrogen evolution with hydrogen-atom transfer: electron-initiated hydrofunctionalization of alkenes
Hydrogen-atom transfer mediated by earth-abundant transition-metal hydrides (M-Hs) has
emerged as a powerful tool in organic synthesis. Current methods to generate M-Hs most …
emerged as a powerful tool in organic synthesis. Current methods to generate M-Hs most …
Unraveling hydrogen atom transfer mechanisms with voltammetry: oxidative formation and reactivity of cobalt hydride
The utility of transition metal hydride catalyzed hydrogen atom transfer (MHAT) has been
widely demonstrated in organic transformations such as alkene isomerization and …
widely demonstrated in organic transformations such as alkene isomerization and …
C H Bond Functionalization through Intramolecular Hydride Transfer
MC Haibach, D Seidel - Angewandte Chemie International …, 2014 - Wiley Online Library
Known for over a century, reactions that involve intramolecular hydride‐transfer events have
experienced a recent resurgence. Undoubtedly responsible for the increased interest in this …
experienced a recent resurgence. Undoubtedly responsible for the increased interest in this …
Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals
SL Shevick, CV Wilson, S Kotesova, D Kim… - Chemical …, 2020 - pubs.rsc.org
Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …
Metal surfaces catalyse polarization-dependent hydride transfer from H2
Hydride transfer is a critical elementary reaction step that spans biological catalysis, organic
synthesis and energy conversion. Conventionally, hydride transfer reactions are performed …
synthesis and energy conversion. Conventionally, hydride transfer reactions are performed …
The high chemofidelity of metal-catalyzed hydrogen atom transfer
SA Green, SWM Crossley, JLM Matos… - Accounts of chemical …, 2018 - ACS Publications
Conspectus The implementation of any chemical reaction in a structurally complex setting
(King, SMJ Org. Chem. 2014, 79, 8937) confronts structurally defined barriers: steric …
(King, SMJ Org. Chem. 2014, 79, 8937) confronts structurally defined barriers: steric …
Recent advances in hydride transfer-involved C (sp 3)–H activation reactions
XD An, J Xiao - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
The hydride transfer reaction, which is characterized by a redox-neutral and step/atom
economic process, has emerged as an enabling platform for C (sp3)–H activation with high …
economic process, has emerged as an enabling platform for C (sp3)–H activation with high …
Hydrogen-atom transfer reactions
L Wang, J Xiao - Hydrogen Transfer Reactions: Reductions and Beyond, 2016 - Springer
Abstract The cascade [1, n]-hydrogen transfer/cyclization, recognized as the tert amino effect
one century ago, has received considerable interest in recent decades, and great …
one century ago, has received considerable interest in recent decades, and great …
Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis
The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the
field of natural product synthesis. MHAT, as a powerful method, has been employed by …
field of natural product synthesis. MHAT, as a powerful method, has been employed by …
C–H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals
Selective functionalization of ubiquitous unactivated C–H bonds is a continuous quest for
synthetic organic chemists. In addition to transition metal catalysis, which typically operates …
synthetic organic chemists. In addition to transition metal catalysis, which typically operates …