Azomethine imines, broadly known as 1, 3-dipoles, efficiently produce synthetically and
biologically significant dinitrogen-fused heterocycles via predominantly concerted or ionic …

We introduce here a two-component annulation strategy that provides access to a diverse
collection of five-and six-membered saturated heterocycles from aryl alkenes and a family of …

A de novo method for direct construction of cyclopenta [b] indolines via a photocatalytic
fluoroalkylative radical cyclization cascade of ynamides has been established, which …

Diazoacetates are widely used to synthesize highly valuable indoles. Previous research has
focused on using metal carbene reactivity or the innate nucleophilicity of the diazoacetates …

In recent years, significant advances have been made on photoredox-catalyzed N-radical
addition to CC unsaturated bond via NH bond cleavage. However, these N-centered radical …

Intramolecular cyclization of nitrogen-containing molecules onto pendant alkenes is an
efficient strategy for the construction of N-heterocycles, which are of paramount importance …

A photocatalytic tandem cyclization of o-alkenylbenzaldehydes using pyridinium salts as the
amination reagent is described. A variety of valuable seven-membered nitrogenous …

The construction and manipulation of amine-containing architectures is of importance to
academic and industrial development and discovery programs. The photochemical single …

The dihydroisoquinolones skeleton is ubiquitous in natural products and biological
molecules. Reported strategies for constructing dihydroisoquinolones usually require noble …

Despite the preliminary success of transition metal‐catalyzed [3+ 2] annulation of amides
with olefins, the corresponding radical‐type [3+ 2] annulation remains a laborious challenge …