We disclose herein a photocatalytic difluoroalkylation and cyclization cascade reaction of N-
(but-2-enoyl) indoles with broad substrate scopes in up to 90% isolated yield. This method …

A visible-light mediated approach to radical difluoromethylation of 3-and 3, 5-substituted
indoles was investigated using a readily synthesized difluoromethyl source, CF 2 HPPh 3 Br …

A process for achieving photocatalyzed tri-and difluoromethylation/cyclizations for
constructing a series of tri-or difluoromethylated indole [2, 1-a] isoquinoline derivatives is …

A visible‐light‐promoted cascade difluoromethylation/cyclization reaction to access various
difluoromethylated pyrrolo [1, 2‐a] indolediones was developed using …

Herein, we describe the synthesis of 5-fluoro-dihydroindolizines via dual C–F bond
cleavage in a trifluoromethyl group. The photocatalytic defluorinative coupling of pyrrole-2 …

An effective method for accessing diverse difluoroalkylated pyrrolo [1, 2-a] indolediones via
visible-light-induced PhI (OAc) 2-promoted cascade difluoroalkylation/cyclization reaction …

We report an efficient method for the synthesis of indoline derivatives via Ir-photocatalytic
radical cascade cyclization, incorporating gem‑difluoroalkylation and C (sp 2)− H …

Arylisonitriles (2 equivalents) react with alkyl and perfluoroalkyl radicals to form 2-alkylated
indole-3-imines via two sequential additions to the isonitrile moiety followed by homolytic …

A red-light-mediated nPr-DMQA+-catalyzed cascade intramolecular trifluoromethylation and
dearomatization of indole derivatives with Umemoto's reagent has been developed. This …

A visible-light induced intramolecular radical cyclization of N-[2-(alkynyl) phenyl]
trifluoroacetimidoyl chlorides is described. The reaction allows the rapid construction of …