A de novo method for direct construction of cyclopenta [b] indolines via a photocatalytic
fluoroalkylative radical cyclization cascade of ynamides has been established, which …

Radical cyclization cascades triggered by a trifluoromethyl radical represent a valuable tool
for accessing highly complex and biologically relevant scaffolds. Herein, we introduce a …

We disclose herein a photocatalytic difluoroalkylation and cyclization cascade reaction of N-
(but-2-enoyl) indoles with broad substrate scopes in up to 90% isolated yield. This method …

A visible-light-mediated radical tandem cyclization of ortho-isocyano-α-bromo cinnamates to
2-substituted indole-3-glyoxylates is achieved by formation of both C–C/C–S and C–O …

An efficient N-centered radical intramolecular cyclization reaction of alkenyl amides induced
by visible light was described. In this process, an alkenyl amide underwent 5-exo/6-endo …

Under photocatalytic reductive conditions, trifluoromethyl radical addition onto an ynamide
followed by cyclization on a benzoyl moiety produces diverse isoindolinone platforms with …

Azomethine imines, broadly known as 1, 3-dipoles, efficiently produce synthetically and
biologically significant dinitrogen-fused heterocycles via predominantly concerted or ionic …

A photoinduced direct synthesis of 3‐amino‐1‐indenones via radical cascade cyclization
strategy is demonstrated. The methodology involves a domino reaction between 2 …

Polycyclic indole scaffolds are ubiquitous in pharmaceuticals and natural products and in
materials science. Here, we present a visible-light-initiated intramolecular aryl migration …

A reagent‐controlled stereodivergent carbocyclisation of aryl aldimine‐derived,
photocatalytically generated, α‐amino radicals possessing adjacent conjugated alkenes …