A general streamlined strategy for the enantioselective total syntheses of the schizozygane
family of natural products and related alkaloid vallesamidine is described. Specifically, a …

The total synthesis of representative members of the schizozygine alkaloids,(+)‐
vallesamidine and (+)‐14, 15‐dehydrostrempeliopine, were completed from a late‐stage …

Covering 1963 to 2023Monoterpene indole alkaloids are the main sub-family of indole
alkaloids with fascinating structures, stereochemistry, and diverse bioactivities (eg …

A generalized synthetic access to sarpagine alkaloids through a joint synthetic sequence
has been accomplished. Its applicability is showcased by the enantioselective total …

This article describes synthetic studies that culminated in the first total synthesis of the
Lycopodium alkaloid sieboldine A. During this study, a number of pinacol-terminated …

Described herein is an account of my laboratory's entry into the magnificent field of complex
alkaloid total synthesis, spanning the development of novel methods for quickly assembling …

The akuammiline alkaloids are a structurally diverse class of bioactive natural products
isolated from plants found in various parts of the world. A particularly challenging subset of …

A concise and highly enantioselective total synthesis of the akuammiline alkaloid (−)-
vincorine has been accomplished. A key element of the synthesis is a stereoselective …

In this article, full details regarding our total synthesis of avrainvillamide and the
stephacidins are presented. After an introduction and summary of prior synthetic studies in …

A concise synthesis of (+)-geissoschizine (1), a biosynthetic precursor of a variety of
monoterpenoid indole alkaloids, from d-tryptophan (19) was performed as a critical prelude …