Roles of plasma-generated vacuum-ultraviolet photons and oxygen radicals in damaging nanoporous low-k films

J Lee, DB Graves - Journal of Vacuum Science & Technology A, 2013 - pubs.aip.org
One important class of low-k materials used as interconnect dielectrics employs methyl
groups added to nanoporous SiO 2 matrices. These carbon-doped oxide materials are …

The effect of VUV radiation from Ar/O2 plasmas on low-k SiOCH films

J Lee, DB Graves - Journal of physics D: Applied physics, 2011 - iopscience.iop.org
The degradation of porous low-k materials, like SiOCH, under plasma processing continues
to be a problem in the next generation of integrated-circuit fabrication. Due to the exposure …

Synergistic damage effects of vacuum ultraviolet photons and O2 in SiCOH ultra-low-k dielectric films

J Lee, DB Graves - Journal of Physics D: Applied Physics, 2010 - iopscience.iop.org
Damage incurred during plasma processing, leading to increases in dielectric constant k, is
a persistent problem with porous ultra-low-k dielectric films, such as SiCOH. Although most …

Fundamental mechanisms of oxygen plasma-induced damage of ultralow-k organosilicate materials: The role of thermal P3 atomic oxygen

M Chaudhari, J Du, S Behera, S Manandhar… - Applied Physics …, 2009 - pubs.aip.org
Fourier transform infrared (FTIR) spectroscopy, x-ray photoelectron spectroscopy (XPS), and
ab initio density functional theory-based molecular dynamics simulations demonstrate …

Damage by radicals and photons during plasma cleaning of porous low-k SiOCH. I. Ar/O2 and He/H2 plasmas

J Shoeb, MM Wang, MJ Kushner - … of Vacuum Science & Technology A, 2012 - pubs.aip.org
Porous dielectric materials offer lower capacitances that reduce RC time delays in integrated
circuits. Typical porous low dielectric (low-k) materials include SiOCH—silicon dioxide with …

The efficacy of post porosity plasma protection against vacuum-ultraviolet damage in porous low-k materials

K Lionti, M Darnon, W Volksen, T Magbitang… - Journal of Applied …, 2015 - pubs.aip.org
As of today, plasma damage remains as one of the main challenges to the reliable
integration of porous low-k materials into microelectronic devices at the most aggressive …

Role of ions, photons, and radicals in inducing plasma damage to ultra low-k dielectrics

H Shi, H Huang, J Bao, J Liu, PS Ho, Y Zhou… - Journal of Vacuum …, 2012 - pubs.aip.org
The damage induced by CO 2 and O 2 plasmas to an ultra low-k (ULK) dielectric film with a
dielectric constant (κ) of 2.2 was investigated. The dielectric constant was observed to …

Damage by radicals and photons during plasma cleaning of porous low-k SiOCH. II. Water uptake and change in dielectric constant

J Shoeb, MJ Kushner - Journal of Vacuum Science & Technology A, 2012 - pubs.aip.org
Porous dielectric materials provide lower capacitances that reduce RC time delays in
integrated circuits. Typical low-k materials include porous SiOCH—silicon dioxide with …

The effects of vacuum ultraviolet radiation on low-k dielectric films

H Sinha, H Ren, MT Nichols, JL Lauer… - Journal of Applied …, 2012 - pubs.aip.org
Plasmas, known to emit high levels of vacuum ultraviolet (VUV) radiation, are used in the
semiconductor industry for processing of low-k organosilicate glass (SiCOH) dielectric …

Modification of porous SiOCH by first contact with water vapor after plasma process

M Darnon, N Rochat, C Licitra - … of Vacuum Science & Technology B, 2015 - pubs.aip.org
Porous low-k dielectrics used in integrated circuits interconnects are sensitive to plasma
processes and exposure to moist ambient. In this paper, the authors use a vacuum and dry …