A reagent‐controlled stereodivergent carbocyclisation of aryl aldimine‐derived,
photocatalytically generated, α‐amino radicals possessing adjacent conjugated alkenes …

A photocatalytic tandem cyclization of o-alkenylbenzaldehydes using pyridinium salts as the
amination reagent is described. A variety of valuable seven-membered nitrogenous …

The radical cascade reaction is considered as one of the most powerful methods to build
molecular complexity. However, highly stereoselective intermolecular radical cascade …

Conspectus Visible-light photocatalysis has recently received increasing attention from
chemists because of its wide application in organic synthesis and its significance for …

The construction and manipulation of amine-containing architectures is of importance to
academic and industrial development and discovery programs. The photochemical single …

The first reductive generation of carbamoyl radicals using photoredox catalysis for their
formation is reported. This approach facilitated the development of a redox-neutral synthesis …

A visible-light-mediated photocatalytic umpolung synthesis of 1, 3-diamines from in situ-
generated imines and dehydroalanine derivatives is described. Pivoting on a key …

We report a controlled radical cyclization cascade of isoquinoline-1, 3, 4 (2 H)-triones, 3-
hydroxyisoindolin-1-ones, and phthalimides from o-alkynylated benzamides by metal-free …

A highly chemo‐and regioselective intermolecular 1, 2‐aryl‐aminoalkylation of alkenes by
photoredox/nickel dual catalysis is described here. This three‐component conjunctive cross …

Visible‐light‐mediated photoredox‐catalyzed aldimine–aniline and aldehyde–aniline
couplings have been realized. The reductive single electron transfer (SET) umpolung of …