Low Thermal Conductivity and High Thermoelectric Performance in (GeTe)1–2x(GeSe)x(GeS)x: Competition between Solid Solution and Phase Separation

M Samanta, K Biswas - Journal of the American Chemical Society, 2017 - ACS Publications
GeTe and its derivatives constituting Pb-free elements have been well known as potential
thermoelectric materials for the last five decades, which offer paramount technological …

Highly tailored gap-like structure for excellent thermoelectric performance

X Xu, Y Huang, X Liu, B Jia, J Cui, R He… - Energy & …, 2022 - pubs.rsc.org
The microstructure-dependent thermal transport property has drawn significant attention in
the thermoelectric community for elevating thermoelectric performance. In this work, we …

Anion-site-modulated thermoelectric properties in Ge2Sb2Te5-based compounds

P Hu, TR Wei, SJ Huang, XG Xia, PF Qiu, J Yang… - Rare Metals, 2020 - Springer
The amalgamation of multi-subjects often elicits novel materials, new concepts and
unexpected applications. Recently, Ge 2 Sb 2 Te 5, as the most established phase-change …

Localized crystal imperfections coupled with phase diagram engineering yield high-performance rhombohedral GeTe thermoelectrics

BC Chen, KK Wang, HJ Wu - Materials Today Physics, 2022 - Elsevier
Cubic β-GeTe alloys are apt to hoist the conversion efficiency for mid-temperature
thermoelectric (TE) generators with their remarkably high peak figure-of-merit (zT) values at …

Raising the solubility of Gd yields superior thermoelectric performance in n-type PbSe

Q Deng, Y Zhong, C Zhao, F Zhang, CL Xia… - Journal of Materials …, 2022 - pubs.rsc.org
Chemical doping is an indispensable means of improving the performance of thermoelectric
materials, while one bottleneck for maximizing optimization is the low solubility of dopants …

Computational prediction of high thermoelectric performance in hole doped layered GeSe

S Hao, F Shi, VP Dravid, MG Kanatzidis… - Chemistry of …, 2016 - ACS Publications
Thermoelectric materials enable direct conversion between thermal and electrical energy
and provide a viable route for power generation and electric refrigeration. In this paper, we …

A first-principles study of the thermoelectric properties of rhombohedral GeSe

K Yuan, Z Sun, X Zhang, X Gong… - Physical Chemistry …, 2020 - pubs.rsc.org
Manipulation of crystal symmetry is an important strategy to tune the thermoelectric
performance. High-symmetry thermoelectric materials benefit from high band degeneracy …

Tailoring 5s2 lone pair-antibonding orbital interaction by Zr-doping to realize ultrahigh power factor in thermoelectric GeTe

X Bai, C Liu, F Li, Z Zhang, Y Peng, R Si, B Feng… - Chemical Engineering …, 2023 - Elsevier
Lead-free GeTe-based thermoelectric (TE) materials are most promising candidates to
replace the environmentally harmful PbTe for TE application at middle temperature range …

Structural modulation and resonant level enable high thermoelectric performance of GeTe in the mid-to-low temperature range

G Wu, Z Guo, R Wang, X Tan, C Cui, P Sun… - Journal of Materials …, 2023 - pubs.rsc.org
GeTe has recently attracted wide attention as a promising mid-temperature thermoelectric
candidate, but the poor performance severely limits its practical application. Herein, we …

Versatile vanadium doping induces high thermoelectric performance in GeTe via band alignment and structural modulation

Q Sun, M Li, XL Shi, SD Xu, WD Liu… - Advanced Energy …, 2021 - Wiley Online Library
Owing to the moderate energy offset between light and heavy band edges of the rock‐salt
structured GeTe, its figure‐of‐merit (ZT) can be enhanced by the rational manipulation of …