(Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with
benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to …

Free borylenes are elusive, highly reactive species that are not accessible under ambient
conditions but can be generated and effectively stabilized in the coordination sphere of …

The reduction of boron–halide bonds has attracted the attention of numerous research
groups for nearly 50 years, with a view to preparing low-coordinate radical or anionic boron …

More and more metal complexes with terminal borylene ligands will be synthesized.
Although these ligands in metal complexes must be stabilized either by integration of the …

Im sich rasch entwickelnden Feld der terminalen Borylenkomplexe beginnen sich erste
faszinierende Reaktivitätsmuster abzuzeichnen, die stark von der partiellen oder …

Heteroboracycles that contain one boron atom, such as borirenes (I),[1] boroles (II),[1c, 2]<
and borepines (III)[3](Figure1) have attracted interest with regard to Hückel aromaticity/anti …

In the rapidly developing field of terminal transition metal borylene complexes, a fascinating
reactivity profile has begun to emerge, which is heavily dominated by reactions involving the …

Walter Hieber s seminal work on metal carbonyl compounds not only established these
complexes as one of the most important classes of organometallics, but also disclosed …

The recent development of the photochemical transfer of borylene ligands from chromium
and tungsten borylene complexes to inorganic,[1] and more recently, organic [2] substrates …

Insertion reactions of unsaturated molecules represent one of the key fundamental reaction
types in organometallic chemistry, with relevance to a number of important catalytic …