Synthesis of methyl glycolate via low‐temperature hydrogenation of dimethyl oxalate over an efficient and stable Ru/activated carbon catalyst

H Zheng, Y Xue, Y Niu, X Gao, Y Wang… - Journal of Chemical …, 2022 - Wiley Online Library
BACKGROUND Syngas to dimethyl oxalate (DMO) followed by hydrogenation to methyl
glycolate (MG) is considered to be an environmentally friendly and economical route …

Cobalt-silver catalyst with low metal content for highly efficient synthesis of methyl glycolate through synergistic effect

F Zheng, J Gong, H Zhang, W Shu, X Wang… - Chemical Engineering …, 2024 - Elsevier
Abstract The Co-Ag x/TiO 2 catalysts with low mass content of Co and Ag were synthesized
through the impregnation method and investigated for dimethyl oxalate (DMO) …

Promoting effect of boron oxide on Ag/SiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate

H Chen, J Tan, J Cui, X Yang, H Zheng, Y Zhu, Y Li - Molecular Catalysis, 2017 - Elsevier
A highly active and stable catalyst for the hydrogenation of dimethyl oxalate (DMO) to methyl
glycolate (MG) had been developed. The Ag-B 2 O 3/SiO 2 catalysts were prepared by …

Efficient hydrogenation of dimethyl oxalate to methyl glycolate over highly active immobilized-ruthenium catalyst

H Fan, J Tan, Y Zhu, H Zheng, Y Li - Journal of Molecular Catalysis A …, 2016 - Elsevier
Highly active and stable catalysts for hydrogenation of dimethyl oxalate (DMO) to methyl
glycolate (MG) were desirable but highly challengeable. In this study, a kind of immobilized …

Synthesis of methyl glycolate by hydrogenation of dimethyl oxalate with a P modified Co/SiO 2 catalyst

Z Zhuang, Y Li, F Chen, X Chen, Z Li, S Wang… - Chemical …, 2022 - pubs.rsc.org
A P-modified Co/SiO2 catalyst was reported for the first time in the selective hydrogenation
of dimethyl oxalate (DMO) to methyl glycolate (MG) reaction and the synthesized Co8P/SiO2 …

Facile synthesis of Cu@ Ag/SiO2 catalysts for the selective hydrogenation of dimethyl oxalate to methyl glycolate

Y Hai, T Guan, Y Feng, Z Zhen, Y Yang, Y Hu… - Chemical Engineering …, 2024 - Elsevier
A promising route for producing biodegradable polyglycolic acid material from syngas has
garnered increasing attentions. In this route, one of the pivotal issues is developing …

Synthesis of methyl glycolate from the hydrogenation of dimethyl oxalate on Ag/SiO2 catalyst: the effects of Ag contents and promoters

S Cheng, D Mao, X Guo, J Yu - Reaction Kinetics, Mechanisms and …, 2019 - Springer
A series of silica supported silver catalysts (Ag/SiO 2) with Ag loading ranging from 5% to
15% were fabricated by the ammonia-evaporation deposition–precipitation method. The …

High-Performance Ni3P/meso-SiO2 for Gas-Phase Hydrogenation of Dimethyl Oxalate to Methyl Glycolate

G Zhao, H Li, J Si, Q Nie, C Meng, Y Liu… - … Sustainable Chemistry & …, 2021 - ACS Publications
Three meso-SiO2 (RB-MSN, HMS, and MCM-41) supported Ni3P catalysts to be used in gas-
phase hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) are prepared via …

Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol

Y Zhao, S Li, Y Wang, B Shan, J Zhang, S Wang… - Chemical Engineering …, 2017 - Elsevier
The chemoselective synthesis of ethylene glycol (EG) from the hydrogenation of dimethyl
oxalate (DMO) derived from syngas is an attractive technology in the modern chemical …

Selective Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Boron-Modified Ag/SiO2 Catalysts

S Cheng, T Meng, D Mao, X Guo, J Yu - ACS omega, 2022 - ACS Publications
The addition of boron (B) as a promoter to the Ag/SiO2 catalyst for the selective
hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) was investigated. A …