Visible-light-mediated tandem radical difluoroalkylation and alkynylation of unactivated
alkenes is described in this communication. The process comprises a mild C–C bond …

Photoredox-catalyzed addition of the difluoromethylradical to unactivated alkenes has been
found to trigger neophyl-like aryl and heteroaryl migrations which allowed the construction of …

Disclosed herein is a novel, redox‐neutral protocol for the visible‐light‐induced radical
alkynylation of unactivated olefins. The intramolecular migration of an alkynyl group, by …

The first example of photoredox catalyzed difluoromethylation of unactivated alkenes
coupled with C–C bond formation to an aryl ring is reported. The reactions are conducted …

Monofluoromethylated compounds exhibit unique physicochemical properties with wide
applications in drug discovery. The direct monofluoromethylation of common feedstocks …

Currently, the selective activation of C (sp3)–F bonds and C–C bonds constitute one of the
most widely used procedures for the synthesis of high-value products that range from …

Visible light-mediated cascade remote oxyfluoroalkylation of alkenes under mild conditions
is developed for the first time. The key point of this transformation is the incorporation of …

A photoredox-catalyzed sequential decarboxylative/defluorinative aminoalkylation of CF3-
alkenes with N-arylglycines is described. This metal-free and redox-neutral protocol …

A photoredox-catalyzed direct difluoromethylation of alkynoates has been developed. A well-
designed photoredox system induces a single-step, regioselective installation of CF2H onto …

An unprecedented and challenging radical–radical cross‐coupling of α‐aminoalkyl radicals
with monofluoroalkenyl radicals derived from gem‐difluoroalkenes was achieved. This first …