The theory of permanent set at elevated temperatures in natural and synthetic rubber vulcanizates

RD Andrews, AV Tobolsky, EE Hanson - Journal of Applied Physics, 1946 - pubs.aip.org
A molecular theory is developed to describe quantitatively the permanent set taking place in
thin samples of vulcanized natural and synthetic rubbers held at constant extension at …

Permanent set in vulcanized rubber

L Mullins - Rubber Chemistry and Technology, 1949 - meridian.allenpress.com
The residual extension which remains after a sample of rubber has been stretched for some
period, then released and allowed to recover, is popularly called permanent set. This set …

Cross-link formation in stretched rubber networks

JP Berry, J Scanlan, WF Watson - Transactions of the Faraday Society, 1956 - pubs.rsc.org
An important property of vulcanized rubber is an increase in the unstrained length after
stretching, the so-called permanent set. When stretching is for short duration at ordinary …

Effects of molecular structure on physical properties of butyl rubber

PJ Flory - Rubber Chemistry and Technology, 1946 - meridian.allenpress.com
The investigation was undertaken in an attempt to establish the fundamental connections
between the physical properties of a typical vulcanized rubberlike polymer and its chemical …

Determination of degree of crosslinking in natural rubber vulcanizates. Part III

L Mullins - Journal of Applied Polymer Science, 1959 - Wiley Online Library
Improvement in methods of characterizing the stress‐strain properties of vulcanized rubber
and of determining its molecular weight prior to vulcanization are described. Experimental …

Dependence of tensile strength of vulcanized rubber on degree of cross‐linking

PJ Flory, N Rabjohn, MC Shaffer - Journal of Polymer Science, 1949 - Wiley Online Library
Tensile strengths of natural rubber samples quantitatively crosslinked with decamethylene
dis‐methyl azodicarboxylate have been determined. The proportion of the azo vulcanizing …

Theory of the increase in rigidity of rubber during cure

HM James, E Guth - The Journal of Chemical Physics, 1947 - pubs.aip.org
The rigidity of rubber, considered as a network of flexible molecules with Gaussian
configuration functions, can be calculated for a particular sample if one is given a complete …

Elastic recovery and plastic flow in raw rubber

LRG Treloar - Rubber Chemistry and Technology, 1940 - meridian.allenpress.com
In considering existing information on the mechanical properties of raw rubber, it is not
generally possible to distinguish between the effects of elastic and of plastic deformation. In …

High temperature vulcanization of elastomers: 2. Network structures in conventional sulphenamide-sulphur natural rubber vulcanizates

CT Loo - Polymer, 1974 - Elsevier
A natural rubber (NR) gum mix with a conventional N-cyclohexyl-2-
benzothiazylsulphenamide (CBS) accelerated sulphur system (0.5: 2.5 CBS/S) was …

The effect of network flaws on the elastic properties of vulcanizates

J Scanlan - Journal of Polymer Science, 1960 - Wiley Online Library
A treatment is given of the effect of network flaws due to the finite chain length of the primary
elastomer molecules on the elastic properties of rubber vulcanizates. In this treatment full …