Radical Deaminative ipso-Cyclization of 4-Methoxyanilines with 1,7-Enynes for Accessing Spirocyclohexadienone-Containing Cyclopenta[c]quinolin-4-ones

J Li, WW Zhang, XJ Wei, F Liu, WJ Hao… - The Journal of …, 2017 - ACS Publications
A new C-center radical-triggered bicyclization cascade of N-tethered 1, 7-enynes for forming
28 examples of biologically interesting spirocyclohexadienone-containing cyclopenta [c] …

Oxidative bicyclization of N-tethered 1, 7-enynes toward polycyclic 3, 4-dihydroquinolin-2 (1 H)-ones via site-selective decarboxylative C (sp 3)–H functionalization

J Li, WJ Hao, P Zhou, YL Zhu, SL Wang, SJ Tu… - RSC advances, 2017 - pubs.rsc.org
A new Ag-catalyzed oxidative bicyclization of N-tethered 1, 7-enynes with alkylcarboxylic
acids for forming 41 examples of polycyclic 3, 4-dihydroquinolin-2 (1H)-ones has been …

Cascade Radical 1,6-Addition/Cyclization of para-Quinone Methides: Leading to Spiro[4.5]deca-6,9-dien-8-ones

R Pan, L Hu, C Han, A Lin, H Yao - Organic letters, 2018 - ACS Publications
A cascade three-component iodoazidation of para-quinone methides to construct spiro [4.5]
deca-6, 9-dien-8-ones under mild conditions has been developed. The chemoselective 1, 6 …

Rh (iii)-catalyzed substrate-dependent oxidative (spiro) annulation of isoquinolones with diazonaphthoquinones: selective access to new spirocyclic and oxepine …

S Guo, Z Zhang, Y Zhu, Z Wei, X Zhang… - Organic Chemistry …, 2022 - pubs.rsc.org
Reported herein is a practical and selective assembly of novel isoquinolone-containing
spirocyclic and oxepine-fused polycyclic skeletons through a rhodium (III)-catalyzed …

Base-mediated diastereoselective [4+ 3] annulation of in situ generated ortho-quinone methides with C, N-cyclic azomethine imines

J Xu, S Yuan, J Peng, M Miao, Z Chen… - Organic & Biomolecular …, 2017 - pubs.rsc.org
An efficient [4+ 3] annulation of 2-(1-tosylalkyl) phenols with C, N-cyclic azomethine imines
via in situ generation of ortho-quinone methides (o-QMs) under mild basic reaction …

Improved Radical Approach to N‐Unsubstituted Indol‐2‐one and Dihydro‐2‐quinolinone Compounds Bearing Spirocyclic Cyclohexanone/Cyclohexadienone Rings

T Lanza, M Minozzi, A Monesi, D Nanni… - Advanced Synthesis …, 2010 - Wiley Online Library
Abstract N‐Unsubstituted indol‐2‐one and 3, 4‐dihydro‐2‐quinolinone compounds bearing
spirocyclic cyclohexanone/cyclohexadienone rings can be accessed through a novel …

Lewis Acid Catalyzed Tandem 1,4-Conjugate Addition/Cyclization of in Situ Generated Alkynyl o-Quinone Methides and Electron-Rich Phenols: Synthesis of …

JY Du, YH Ma, FX Meng, BL Chen, SL Zhang… - Organic …, 2018 - ACS Publications
A versatile Lewis acid catalyzed tandem cyclization of in situ generated alkynyl o-quinone
methides (o-AQMs) with electron-rich phenols has been developed on the basis of the mode …

PIFA-Mediated oxidative cyclization of 1-aroyl-N-arylcyclopropane-1-carboxamides and their application in the synthesis of pyrrolo [3, 2-c] quinolinones

Z Zhang, X Gao, Z Li, G Zhang, N Ma, Q Liu… - Organic Chemistry …, 2017 - pubs.rsc.org
An efficient ring-closing reaction was developed for the synthesis of spirocyclopropane
quinolinediones from 2, 2-disubstituted 2-benzoylacetamides in the presence of [bis …

Dimethyl Sulfoxide and N-Iodosuccinimide Promoted 5-exo-dig Oxidative Cyclization of Yne-Tethered Ynamide: Access to Pyrrolidones and Spiro-pyrrolidones

B Prabagar, S Nayak, R Prasad, AK Sahoo - Organic letters, 2016 - ACS Publications
An unprecedented metal-free dimethyl sulfoxide (DMSO) and N-iodosuccinimide mediated
regioselective 5-exo-dig oxidative cyclization of an in situ generated enol equivalent of …

Hydroxyalkylation-Initiated Radical Cyclization of N-Allylbenzamide for Direct Construction of Isoquinolinone

W Zhou, S Ni, H Mei, J Han, Y Pan - Organic letters, 2015 - ACS Publications
A metal-free hydroxyalkylation-initiated radical six-membered heterocycle formation reaction
of N-allylbenzamide is developed. This reaction proceeds through C (sp3)–H bond …