Density-functional theory study on hydrogenation of dimethyl oxalate to methyl glycolate over copper catalyst: Effect of copper valence state

J An, X Wang, J Zhao, S Jiang, Y Quan, Y Pei, M Wu… - Molecular …, 2020 - Elsevier
The development of high-performance copper (Cu)-based catalysts is critical to achieve the
industrial hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG). To understand …

Efficient Descriptor for Designing High-Performance Cu-Based Catalysts for the Hydrogenation of Dimethyl Oxalate to Methyl Glycolate

T Xiao, Z Yang, Z Zhen, Y Yang, Y Hu… - The Journal of …, 2024 - ACS Publications
The semihydrogenation of dimethyl oxalate (DMO) into methyl glycolate (MG) has garnered
increasing attention in the production of the biodegradable polymer material, polyglycolic …

The Nature of Active Copper Species in Cu-HMS Catalyst for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol: New Insights on the Synergetic Effect between Cu0 and Cu …

A Yin, X Guo, WL Dai, K Fan - The Journal of Physical Chemistry …, 2009 - ACS Publications
Copper-containing mesoporous HMS catalysts prepared via a one-pot synthesis method
based on sol− gel chemistry have been systematically characterized focusing on the effect of …

Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol

Y Zhao, S Li, Y Wang, B Shan, J Zhang, S Wang… - Chemical Engineering …, 2017 - Elsevier
The chemoselective synthesis of ethylene glycol (EG) from the hydrogenation of dimethyl
oxalate (DMO) derived from syngas is an attractive technology in the modern chemical …

Effect of Cu loading on the structural evolution and catalytic activity of Cu–Mg/ZnO catalysts for dimethyl oxalate hydrogenation

X Kong, Y Wu, L Ding, R Wang, J Chen - New Journal of Chemistry, 2020 - pubs.rsc.org
The influence of Cu loading on the structural evolution and catalytic behavior in selective
hydrogenation of dimethyl oxalate (DMO) by Mg2+ doped nanoscaled Cu–Mg/ZnO catalysts …

Toward rational catalyst design for partial hydrogenation of dimethyl oxalate to methyl glycolate: a descriptor-based microkinetic analysis

WQ Yan, JB Zhang, L Xiao, YA Zhu, YQ Cao… - Catalysis Science & …, 2019 - pubs.rsc.org
Partial hydrogenation of dimethyl oxalate (DMO) has attained increasing attention in the
chemical industry, which is driven by the desire to develop a means of achieving methyl …

Facile synthesis of Cu@ Ag/SiO2 catalysts for the selective hydrogenation of dimethyl oxalate to methyl glycolate

Y Hai, T Guan, Y Feng, Z Zhen, Y Yang, Y Hu… - Chemical Engineering …, 2024 - Elsevier
A promising route for producing biodegradable polyglycolic acid material from syngas has
garnered increasing attentions. In this route, one of the pivotal issues is developing …

Perspectives on the active sites and catalyst design for the hydrogenation of dimethyl oxalate

RP Ye, L Lin, LC Wang, D Ding, Z Zhou, P Pan… - ACS …, 2020 - ACS Publications
What should people do with the huge amount of CO2 captured? CO2 to CO is a promising
way for using carbon resources because CO is one component of syngas for the production …

Identification of Synergistic Actions between Cu0 and Cu+ Sites in Hydrogenation of Dimethyl Oxalate from Microkinetic Analysis

WQ Yan, JB Zhang, RJ Zhou, YQ Cao… - Industrial & …, 2020 - ACS Publications
The kinetics of dimethyl oxalate (DMO) hydrogenation over Cu (111) and Cu2O (111) has
been studied to understand the role of Cu0 and Cu+ sites in ethyl glycol (EG) production …

[HTML][HTML] Synthesis of Cu–Mg/ZnO catalysts and catalysis in dimethyl oxalate hydrogenation to ethylene glycol: enhanced catalytic behavior in the presence of a Mg 2+ …

X Kong, Z Chen, Y Wu, R Wang, J Chen, L Ding - RSC advances, 2017 - pubs.rsc.org
Mg2+ doped nanoscale Cu–Mg/ZnO catalysts prepared by the co-precipitation method have
been systematically characterized focusing on the amount of Mg2+ ions incorporated. The …