Inline Raman Spectroscopy of an Emulsion Copolymerization in an Industrial Pilot Plant Using Indirect Hard Modeling

JMM Faust, W Gerlinger, O Naeem… - Chemie Ingenieur …, 2022 - Wiley Online Library
Raman spectroscopy is used to determine the concentrations of monomers and polymers in
the second stage of a two‐stage emulsion polymerization process. The indirect hard …

Monitoring of emulsion polymerization reactors by Raman spectroscopy: calibration model maintenance

O Elizalde, JM Asua, JR Leiza - Applied spectroscopy, 2005 - opg.optica.org
Fourier transform (FT)-Raman combined with partial least squares regression (PLS-R)
calibration models allows the accurate monitoring of solids content, copolymer composition …

Comparing near infrared and Raman spectroscopy for on‐line monitoring of emulsion copolymerization reactions

MM Reis, PHH Araujo, C Sayer… - Macromolecular …, 2004 - Wiley Online Library
In this work, Raman and Near InfraRed (NIR) spectroscopies are evaluated for the
monitoring of different semicontinuous emulsion homo‐and co‐polymerization reactions …

Monitoring emulsion homopolymerization reactions using FT-Raman spectroscopy

MM Reis, M Uliana, C Sayer, PHH Araujo… - Brazilian Journal of …, 2005 - SciELO Brasil
The present work describes a methodology for estimation of monomer concentration during
homopolymerization reactions by Raman spectroscopy. The estimation is done using linear …

Development of calibration models for estimation of monomer concentration by Raman spectroscopy during emulsion polymerization: Facing the medium …

MM Reis, PHH Araujo, C Sayer… - Journal of applied …, 2004 - Wiley Online Library
This work compares different calibration models for the estimation of monomer
concentrations by Raman spectroscopy during semicontinuous emulsion copolymerization …

On‐line monitoring of all‐acrylic emulsion polymerization reactors by Raman spectroscopy

O Elizalde, JR Leiza, JM Asua - Macromolecular Symposia, 2004 - Wiley Online Library
Abstract Fourier Transform Raman spectroscopy was used as an on‐line sensor in order to
monitor high solids content (50 wt%) n‐BA/MMA emulsion copolymerization reactions. Due …

In situ near-infrared spectroscopy for simultaneous monitoring of multiple process variables in emulsion copolymerization

MM Reis, PHH Araújo, C Sayer… - Industrial & engineering …, 2004 - ACS Publications
In this work near-infrared spectroscopy is used to monitor semicontinuous styrene/butyl
acrylate emulsion copolymerization reactions. A set of nine reactions with slightly different …

Monitoring of seeded batch, semi‐batch, and second stage emulsion polymerization by low resolution Raman spectroscopy

TR McCaffery, YG Durant - Polymer Reaction Engineering, 2003 - Taylor & Francis
Low resolution Raman spectroscopy (LRRS) offers a convenient way to monitor many
different polymerization processes and reactor environments. LRRS can be used as an …

Remote in-line monitoring of emulsion polymerization of styrene by short-wavelength near-infrared spectroscopy. 1. Performance during normal runs

CC Wu, JDS Danielsen, JB Callis, M Eaton… - Process Control …, 1996 - hero.epa.gov
Near-infrared (NIR) spectroscopy in the wavelength range 700-1100 nm is used with an in-
line fiber-optic diffuse reflectance probe to monitor the emulsion polymerization of styrene. A …

Correlation between Polymer Particle Size and in‐situ NIR Spectra

MM Reis, PHH Araújo, C Sayer… - Macromolecular rapid …, 2003 - Wiley Online Library
This work describes the estimation of polymer particle size from NIR spectra collected in situ
and online in an automated reactor. A good linearity between spectra and average polymer …