High temperature oxidation of formaldehyde and formyl radical: A study of 1, 3, 5-trioxane laminar burning velocities

J Santner, FM Haas, FL Dryer, Y Ju - Proceedings of the Combustion …, 2015 - Elsevier
Few studies of formaldehyde flames are available, especially at pressures greater than 55
torr, due to the difficulties and hazards associated with producing formaldehyde vapor. This …

Effect of prompt dissociation of formyl radical on 1, 3, 5-trioxane and CH2O laminar flame speeds with CO2 dilution at elevated pressure

H Zhao, J Fu, FM Haas, Y Ju - Combustion and Flame, 2017 - Elsevier
Many studies of the flame speed of hydrocarbon and oxygenated fuels show that flame
speed is very sensitive to formyl radical (HCO) reactions with small species, such as HCO+ …

Ramifications of including non-equilibrium effects for HCO in flame chemistry

NJ Labbe, R Sivaramakrishnan, CF Goldsmith… - Proceedings of the …, 2017 - Elsevier
The formation and destruction pathways of the formyl radical (HCO) occupy a pivotal role in
the conversion of fuel molecules (and their intermediates) to eventual products CO and CO …

Kinetic modelling of the oxidation of carbon monoxide in flames

MA Cherian, P Rhodes, RJ Simpson… - Symposium (International …, 1981 - Elsevier
Implicit solutions of the time-dependent flame equations have been used to calculate, for
assumed reaction mechanisms, the properties of a series of hydrogen/carbon …

Determination of rate coefficients for reactions of formaldehyde pyrolysis and oxidation in the gas phase

B Eiteneer, CL Yu, M Goldenberg… - The Journal of Physical …, 1998 - ACS Publications
Seven mixtures of formaldehyde and oxygen diluted in argon were studied behind reflected
shock waves at temperatures from 1340 to 2270 K and pressures from 0.7 to 2.5 atm …

A comprehensive study on CH2O oxidation kinetics

S Hochgreb, FL Dryer - Combustion and flame, 1992 - Elsevier
Results of calculations based on a detailed chemical mechanism for the oxidation of
formaldehyde are compared with data from a variety of experimental conditions: flow reactor …

Decomposition of 1, 3, 5-trioxane at 700-800 K

S Hochgreb, FL Dryer - The Journal of Physical Chemistry, 1992 - ACS Publications
The unimolecular decomposition of 1, 3, 5-trioxane into formaldehyde is studied
experimentally in the temperature range 700-800 K in an atmospheric pressure flow reactor …

Kinetics in a lean formaldehyde flame

J Vandooren, LO de Guertechin, PJ Van Tiggelen - Combustion and flame, 1986 - Elsevier
The structure of a lean formaldehyde-oxygen flame burning at 22.5 Torr has been
investigated experimentally using molecular beam sampling coupled with mass …

Shock-tube studies of formaldehyde oxidation

AM Dean, RL Johnson, DC Steiner - Combustion and Flame, 1980 - Elsevier
Reflected shock waves were used to heat a variety of formaldehyde mixtures to
temperatures of 1600–3000 K at total concentrations near 5× 10 18/cm 3. Formaldehyde …

A comprehensive kinetic mechanism for CO, CH2O, and CH3OH combustion

J Li, Z Zhao, A Kazakov, M Chaos… - … Journal of Chemical …, 2007 - Wiley Online Library
New experimental profiles of stable species concentrations are reported for formaldehyde
oxidation in a variable pressure flow reactor at initial temperatures of 850–950 K and at …