Recent advances in hydrometallation of alkenes and alkynes via the first row transition metal catalysis

J Chen, J Guo, Z Lu - Chinese Journal of Chemistry, 2018 - Wiley Online Library
Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

Metal-catalyzed Markovnikov-type selective hydrofunctionalization of terminal alkynes

J Chen, WT Wei, Z Li, Z Lu - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …

First-row late transition metals for catalytic alkene hydrofunctionalisation: recent advances in CN, CO and CP bond formation

S Bezzenine-Lafollée, R Gil, D Prim, J Hannedouche - Molecules, 2017 - mdpi.com
This review provides an outline of the most noteworthy achievements in the area of CN, CO
and CP bond formation by hydroamination, hydroalkoxylation, hydrophosphination …

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

XX Wang, X Lu, Y Li, JW Wang, Y Fu - Science China Chemistry, 2020 - Springer
The use of simple and easily available feedstock to quickly and efficiently obtain compounds
with complex molecular structures through the transition-metal-catalyzed construction of C …

Recent Advances in Cobalt-Catalyzed Regio-or Stereoselective Hydrofunctionalization of Alkenes and Alkynes

Y Li, X Lu, Y Fu - CCS Chemistry, 2024 - chinesechemsoc.org
Hydrofunctionalization of alkenes and alkynes is increasingly important in preparing and
modifying carbon-centered organic molecules such as pharmaceuticals, agrochemicals, and …

Hydroamination and hydroaminoalkylation of alkenes by group 3–5 elements: recent developments and comparison with late transition metals

J Hannedouche, E Schulz - Organometallics, 2018 - ACS Publications
This short review highlights recent catalyst developments from group 3–5 elements reported
in the past few years to promote two highly atom-saving transformations, namely …

Early transition metal (group 3–5, lanthanides and actinides) and main group metal (group 1, 2, and 13) catalyzed hydroamination

AL Reznichenko, KC Hultzsch - Hydrofunctionalization, 2013 - Springer
The hydroamination of alkenes, dienes, allenes, and alkynes by early transition metal
catalysts has seen significant progress over the last decade, especially with respect to …

Recent advances in tridentate iron and cobalt complexes for alkene and alkyne hydrofunctionalizations

H Wen, G Liu, Z Huang - Coordination Chemistry Reviews, 2019 - Elsevier
The economical and sustainable nature of base metals has recently inspired extensive
investigations on the development of iron and cobalt catalysts for alkene and alkyne …

Copper-catalyzed hydroalkylation of terminal alkynes

MR Uehling, AM Suess, G Lalic - Journal of the American …, 2015 - ACS Publications
We have developed a copper-catalyzed hydroalkylation of terminal alkynes using alkyl
triflates as coupling partners and (Me2HSi) 2O as a hydride donor. The hydroalkylation …

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

J Chen, Z Lu - Organic Chemistry Frontiers, 2018 - pubs.rsc.org
In recent years, earth-abundant transition metal catalysts have been used to make great
achievements on homogenous catalysis, including the field of enantioselective …