Effect of prompt dissociation of formyl radical on 1, 3, 5-trioxane and CH2O laminar flame speeds with CO2 dilution at elevated pressure

H Zhao, J Fu, FM Haas, Y Ju - Combustion and Flame, 2017 - Elsevier
Many studies of the flame speed of hydrocarbon and oxygenated fuels show that flame
speed is very sensitive to formyl radical (HCO) reactions with small species, such as HCO+ …

Ramifications of including non-equilibrium effects for HCO in flame chemistry

NJ Labbe, R Sivaramakrishnan, CF Goldsmith… - Proceedings of the …, 2017 - Elsevier
The formation and destruction pathways of the formyl radical (HCO) occupy a pivotal role in
the conversion of fuel molecules (and their intermediates) to eventual products CO and CO …

High temperature oxidation of formaldehyde and formyl radical: A study of 1, 3, 5-trioxane laminar burning velocities

J Santner, FM Haas, FL Dryer, Y Ju - Proceedings of the Combustion …, 2015 - Elsevier
Few studies of formaldehyde flames are available, especially at pressures greater than 55
torr, due to the difficulties and hazards associated with producing formaldehyde vapor. This …

Weakly bound free radicals in combustion:“Prompt” dissociation of formyl radicals and its effect on laminar flame speeds

NJ Labbe, R Sivaramakrishnan… - The journal of …, 2016 - ACS Publications
Weakly bound free radicals have low-dissociation thresholds such that at high temperatures,
time scales for dissociation and collisional relaxation become comparable, leading to …

Laminar flame speeds of H2/CO with CO2 dilution at normal and elevated pressures and temperatures

M Han, Y Ai, Z Chen, W Kong - Fuel, 2015 - Elsevier
Laminar flame speeds and Markstein lengths of H 2/CO with CO 2 dilution were measured at
normal and elevated pressures (0.1 MPa, 0.5 MPa, 1.0 MPa) and temperatures (298 K, 375 …

Investigation of combustion enhancement by ozone additive in CH4/air flames using direct laminar burning velocity measurements and kinetic simulations

ZH Wang, L Yang, B Li, ZS Li, ZW Sun, M Aldén… - Combustion and …, 2012 - Elsevier
The effect of ozone additive on the enhancement of the burning velocity for premixed
methane–air flames is investigated by both experimental measurements and kinetic …

Experimental and kinetic modeling investigation on laminar flame propagation of CH4/CO mixtures at various pressures: Insight into the transition from CH4-related …

X Zhang, B Mei, S Ma, H Pan, H Wang, Y Li - Combustion and Flame, 2019 - Elsevier
In this work, laminar flame speeds of CH 4/CO/air mixtures were measured at the unburnt
temperature of 353 K and pressures from 1 to 10 atm in a high-pressure constant-volume …

Calculated impacts of diluents on flame temperature, ignition delay, and flame speed of methane–oxygen mixtures at high pressure and low to moderate temperatures

FB Shareh, G Silcox, EG Eddings - Energy & Fuels, 2018 - ACS Publications
Oxy-fuel combustion is one method to produce concentrated streams of carbon dioxide for
subsequent sequestration. An additional benefit of oxy-firing is a reduction in NO x …

Effects of CO addition on laminar flame characteristics and chemical reactions of H2 and CH4 in oxy-fuel (O2/CO2) atmosphere

Y Xie, N Lv, Q Li, J Wang - International Journal of Hydrogen Energy, 2020 - Elsevier
An experimental study is conducted to investigate the effect of CO addition on the laminar
flame characteristics of H 2 and CH 4 flames in a constant-volume combustion system. In …

Laminar flame speed of CO2 and N2 diluted H2/CO/air flames

R Shang, Y Zhang, M Zhu, Z Zhang, D Zhang… - International Journal of …, 2016 - Elsevier
The laminar flame speeds of H 2/CO/air mixtures with N 2 and CO 2 dilution were
experimentally and numerically studied over a wide range equivalence ratios (0.8–4.0) with …