Hard and soft X-ray microscopy and tomography in catalysis: bridging the different time and length scales

JD Grunwaldt, CG Schroer - Chemical Society Reviews, 2010 - pubs.rsc.org
X-Ray microscopic techniques are excellent and presently emerging techniques for
chemical imaging of heterogeneous catalysts. Spatially resolved studies in heterogeneous …

Hard X‐ray spectroscopic nano‐imaging of hierarchical functional materials at work

JC Andrews, BM Weckhuysen - ChemPhysChem, 2013 - Wiley Online Library
Heterogeneous catalysts often consist of an active metal (oxide) in close contact with a
support material and various promoter elements. Although macroscopic properties, such as …

Catalysts at work: From integral to spatially resolved X-ray absorption spectroscopy

JD Grunwaldt, B Kimmerle, A Baiker, P Boye… - Catalysis Today, 2009 - Elsevier
Spectroscopic studies on heterogeneous catalysts have mostly been done in an integral
mode. However, in many cases spatial variations in catalyst structure can occur, eg during …

Imaging catalysts at work: a hierarchical approach from the macro‐to the meso‐and nano‐scale

JD Grunwaldt, JB Wagner… - ChemCatChem, 2013 - Wiley Online Library
This review highlights the importance of developing multi‐scale characterisation techniques
for analysing operating catalysts in their working environment. We emphasise that a …

Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy

E de Smit, I Swart, JF Creemer, GH Hoveling, MK Gilles… - Nature, 2008 - nature.com
The modern chemical industry uses heterogeneous catalysts in almost every production
process. They commonly consist of nanometre-size active components (typically metals or …

Spatial and temporal exploration of heterogeneous catalysts with synchrotron radiation

F Meirer, BM Weckhuysen - Nature Reviews Materials, 2018 - nature.com
Solid catalysts are the workhorses that convert feedstock molecules into fuels, chemicals
and materials. Solid catalysts are highly complex, porous, multi-elemental and often …

X-ray absorption spectroscopy under reaction conditions: suitability of different reaction cells for combined catalyst characterization and time-resolved studies

JD Grunwaldt, M Caravati, S Hannemann… - Physical Chemistry …, 2004 - pubs.rsc.org
Structure–activity correlations of solid catalysts and time-resolved studies generally require
that the structure within a solid catalyst is probed simultaneously and at the same location …

Challenges and opportunities for applications of advanced X-ray spectroscopy in catalysis research

GE Cutsail III, S DeBeer - ACS Catalysis, 2022 - ACS Publications
X-ray spectroscopy has had a significant and continually growing impact on catalysis
research for nearly 50 years. In particular, the ability to obtain element selective electronic …

Hard X‐ray Nanotomography of Catalytic Solids at Work

ID Gonzalez‐Jimenez, K Cats, T Davidian… - Angewandte …, 2012 - Wiley Online Library
Advances in microscopy such as a spatial resolution in the nanometer range combined with
higher chemical and morphological sensitivities have improved the imaging of functional …

In‐situ scanning transmission X‐ray microscopy of catalytic solids and related nanomaterials

FMF de Groot, E de Smit… - …, 2010 - Wiley Online Library
The present status of in‐situ scanning transmission X‐ray microscopy (STXM) is reviewed,
with an emphasis on the abilities of the STXM technique in comparison with electron …