An efficient N-centered radical intramolecular cyclization reaction of alkenyl amides induced
by visible light was described. In this process, an alkenyl amide underwent 5-exo/6-endo …

Polycyclic indole scaffolds are ubiquitous in pharmaceuticals and natural products and in
materials science. Here, we present a visible-light-initiated intramolecular aryl migration …

Based on the importance of the two classes of nitrogen-containing heterocyclic structures,
isoindolinones and isoquinolinones, herein, through intramolecular cascade cyclization via …

A visible-light photoredox synthesis of 3-acylindoles through intramolecular oxidative
cyclization of o-alkynylated N, N-dialkylamines is developed. The reaction proceeds …

A photoinduced direct synthesis of 3‐amino‐1‐indenones via radical cascade cyclization
strategy is demonstrated. The methodology involves a domino reaction between 2 …

A de novo method for direct construction of cyclopenta [b] indolines via a photocatalytic
fluoroalkylative radical cyclization cascade of ynamides has been established, which …

We report a controlled radical cyclization cascade of isoquinoline-1, 3, 4 (2 H)-triones, 3-
hydroxyisoindolin-1-ones, and phthalimides from o-alkynylated benzamides by metal-free …

Conspectus The monoterpene indole alkaloids, containing over 3000 known members and
more than 40 structural types, represent one of the largest natural product families that have …

Preparation of biologically relevant 3-hydroxyisoindolinones from readily available 2-
alkynylbenzamides is an appealing synthetic approach. However, such kinds of compounds …

Presented herein is an effective and sustainable synthesis of O-heterocycle spiro-fused
cyclopentaquinolinone and cyclopentaindene derivatives through light-driven cascade …