Visible-light induced divergent dearomatization of indole derivatives: controlled access to cyclobutane-fused polycycles and 2-substituted indolines

W Zhuang, YZ Cheng, XL Huang, Q Huang… - Organic Chemistry …, 2021 - pubs.rsc.org
A photocatalytic protocol for the divergent dearomative functionalization of indole derivatives
is reported. Under the irradiation of visible light, either dimerization or reduction occurs …

Photoredox-catalyzed intermolecular hydroalkylative dearomatization of electron-deficient indole derivatives

XL Huang, YZ Cheng, X Zhang, SL You - Organic Letters, 2020 - ACS Publications
Dearomatization of indole derivatives offers a straightforward approach to access diverse
indolines. To date, the corresponding dearomative transformations involving electron …

Visible-light-induced dearomative oxamination of indole derivatives and dearomative amidation of phenol derivatives

L Wu, Y Hao, Y Liu, H Song, Q Wang - Chemical Communications, 2020 - pubs.rsc.org
Herein, we report a protocol for visible-light-induced dearomative oxamination reactions of
indole derivatives to afford functionalized spirocyclic products. These step-economical …

Visible-light enabled synthesis of cyclopropane-fused indolines via dearomatization of indoles

XL Huang, YZ Cheng, SL You - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
An efficient synthesis of methylene-unsubstituted cyclopropane-fused indolines via
photoredox catalyzed dearomative cyclopropanation of indole derivatives was developed. A …

Visible-light-induced intermolecular dearomative cyclization of 2-bromo-1, 3-dicarbonyl compounds and alkynes: Synthesis of spiro [4.5] deca-1, 6, 9-trien-8-ones

W Dong, Y Yuan, X Gao, M Keranmu, W Li, X Xie… - Organic …, 2018 - ACS Publications
A visible-light-induced photocatalytic intermolecular dearomative cyclization of 2-bromo-1, 3-
dicarbonyl compounds and alkynes afforded biologically important spirocarbocycle …

Energy-transfer-enabled dearomative cycloaddition reactions of indoles/pyrroles via excited-state aromatics

M Zhu, X Zhang, C Zheng, SL You - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Exploring the enormous chemical space through an expedient building-up of
molecular diversity is an important goal of organic chemistry. The development of synthetic …

Visible light-induced intramolecular dearomative cyclization of α-bromo-N-benzyl-alkylamides: efficient construction of 2-azaspiro [4.5] decanes

B Hu, Y Li, W Dong, K Ren, X Xie, J Wan… - Chemical …, 2016 - pubs.rsc.org
Visible light-induced intramolecular dearomative cyclization of α-bromo- N -benzyl-alkylamides:
efficient construction of 2-azaspiro[4.5]decanes - Chemical Communications (RSC Publishing) …

Visible‐light‐induced dearomatizations

M Okumura, D Sarlah - European journal of organic chemistry, 2020 - Wiley Online Library
The dearomatization of aromatic compounds is an important synthetic strategy used in
accessing complex three‐dimensional structures from simple aromatic precursors. This …

Arenophile-mediated photochemical dearomatization of nonactivated arenes

M Okumura, D Sarlah - Chimia, 2020 - chimia.ch
Aromatic compounds are one of the most abundant classes of organic molecules and find
utility as precursors for alicyclic hydrocarbon building blocks. While many established …

Visible‐Light‐Induced Intramolecular Double Dearomative Cycloaddition of Arenes

M Zhu, H Xu, X Zhang, C Zheng… - Angewandte Chemie, 2021 - Wiley Online Library
Herein we report visible‐light‐induced intramolecular double dearomative cycloaddition of
arenes. Compared with the well‐known photodimerization of arenes under ultraviolet …