Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of
cycloalkanol-substituted styrenes with N-acyloxyphthalimides and O-acyl oximes have been …

A visible light photoredox-catalyzed N-centered radical addition/semipinacol rearrangement
cascade of cycloalkanol-substituted 1H-indenes or styrenes with N-arylsulfonyl protected 1 …

A novel method for the mild photoredox‐mediated tandem radical acylarylation and tandem
acylation/semipinacol rearrangement has been developed. The synthesis of highly …

The radical difunctionalization of alkenes with sulfonyl bifunctional represents a powerful
and straightforward approach to access functionalized alkane derivatives. However, both the …

A novel photoredox catalysis for multiple functionalization of two different types of
unactivated alkenes in a single operation was reported through a conceptually new mode of …

The In (OTf) 3-promoted three-component photoredox alkylarylation of styrenes with alkyl
NHP esters and arenes to access alkylated arene derivatives through C–C bond cleavage …

Generation of a ketyl radical from unactivated aliphatic carbonyl compounds is an important
strategy in organic synthesis. Herein, catalytic generation and use of a ketyl radical for the …

The oxidative coupling of photogenerated alkyl radicals with readily available styrenes is
disclosed. This visible-light-mediated method allows rapid access to a wide range of α-alkyl …

A radical relay strategy is described to synthesize functionalized β-amino alcohols. This
strategy is enabled by photoredox-catalyzed and nitrogen-centered radical-triggered …

Radical formation is the initial step for conventional radical chemistry. Reported herein is a
unified strategy to generate radicals in situ from aromatic β‐ketoesters by using a …