The spectroscopic properties of the high-spin Fe (III)− alkylperoxo model complex [Fe (6-
Me3TPA)(OH x)(OOtBu)] x+(1; TPA= tris (2-pyridylmethyl) amine, tBu= tert-butyl, x= 1 or 2) …

The spectroscopic properties, electronic structure, and reactivity of the low-spin Fe (III)−
alkylperoxo model complex [Fe (TPA)(OH x)(OOtBu)] x+(1; TPA= tris (2-pyridylmethyl) …

The spectroscopic properties and electronic structure of the four-coordinate high-spin [FeIII
(L3)(OOtBu)]+ complex (1; L3= hydrotris (3-tert-butyl-5-isopropyl-1-pyrazolyl) borate; tBu …

The reactions of iron (II) complexes [Fe (Tp t-Bu, i-Pr)(OH)](1a, Tp t-Bu, i-Pr= hydrotris (3-tert-
butyl-5-isopropyl-1-pyrazolyl) borate),[Fe (6-Me2BPMCN)(OTf) 2](1b, 6-Me2BPMCN= N, N ' …

The mechanism of the alkylperoxo O–O bond cleavage of low-spin iron (III)–alkylperoxo
species has been well established in nonheme iron models. In contrast, the alkylperoxo O …

Low-spin mononuclear (alkylperoxo) iron (III) complexes decompose by peroxide O− O
bond homolysis to form iron (IV) species. We examined the kinetics of previously reported …

High spin oxoiron (IV) complexes have been proposed to be a key intermediate in numerous
nonheme metalloenzymes. The successful detection of similar complexes has been …

We demonstrate the application of infrared photodissocation spectroscopy for determination
of the Fe O stretching frequencies of high-valent iron (IV)–oxo complexes [(L) Fe (O)(X)] …

A mononuclear non-heme iron (III)–peroxo complex,[Fe (III)(O2)(13-TMC)]+(1), was
synthesized and characterized spectroscopically; the characterization with electron …

The spectroscopic properties, electronic structure, and reactivity of the low-spin Fe (III)−
hydroperoxo complex [Fe (N4Py)(OOH)] 2+(1, N4Py= N, N-bis (2-pyridylmethyl)-N-bis (2 …