An unprecedented metal-free dimethyl sulfoxide (DMSO) and N-iodosuccinimide mediated
regioselective 5-exo-dig oxidative cyclization of an in situ generated enol equivalent of …

A straightforward regioselective intramolecular 6-endo-dig cyclization of yne-tethered
ynamide is herein developed. The reaction involves an intramolecular enolate attack of …

An efficient radical cyclization of suitably functionalized ynamides to nitrogen-containing
heterocycles is reported. Upon reaction with tributyltin hydride in the presence of catalytic …

A highly convenient copper (I)-catalyzed oxidation-initiated cyclopropanation of indolyl
ynamide for the rapid construction of indole-fused cyclopropane-lactams is described, which …

An oxidative-decarboxylative intramolecular cyclisation of dipeptide derivatives is reported.
This transformation is promoted by phenyl iodine (III) diacetate (PIDA) in combination with …

Iodocyclization of ethoxyethyl ethers to ynamides was developed to form six, seven-, and
eight-membered cyclic ethers. These reactions reached completion within short reaction …

A new C-center radical-triggered bicyclization cascade of N-tethered 1, 7-enynes for forming
28 examples of biologically interesting spirocyclohexadienone-containing cyclopenta [c] …

Transition‐metal‐free regioselective synthesis of functionalized amino‐indenones by the
reaction of ortho‐alkynylaldehydes with a broad range of primary amines by intramolecular …

Traditional methods for the transformation of N-allyl ynamides rely on the formation of a
ketenimine intermediate or its equivalent, while novel reaction modes remain to be …

Radical Cyclization Cascade Involving Ynamides: An Original Access to Nitrogen-Containing
Heterocycles | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In …