Synthesis and characterization of bis (imino) pyridine complexes of divalent Mg and Zn

TW Myers, TJ Sherbow, JC Fettinger, LA Berben - Dalton Transactions, 2016 - pubs.rsc.org
Phenyl-bis (imino) pyridine (PhI2P) complexes,(PhI2P) ZnCl2 (1),(PhI2P−) ZnCl (2) and
(PhI2P−) Zn (py) Cl (3) were obtained with the I2P ligand in both the neutral and the one …

2, 6-Diiminopyridine complexes of group 2 metals: synthesis, characterisation and redox behaviour

MJC Dawkins, AN Simonov, C Jones - Dalton Transactions, 2020 - pubs.rsc.org
Treatment of the 2, 6-diiminopyridine, NC5H3 {C (Ph) N (Dip)} 2-2, 6 (PhDimpy, Dip= 2, 6-
diisopropylphenyl) with [MgI2 (OEt2) 2] gives the adduct complex [(PhDimpy) MgI2] in which …

Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)

B de Bruin, E Bill, E Bothe, T Weyhermüller… - Inorganic …, 2000 - ACS Publications
A series of mononuclear, octahedral first-row transition metal ion complexes mer-
[MIIL02](PF6) 2 containing the tridentate neutral ligand 2, 6-bis [1-(4-methoxyphenylimino) …

[PDF][PDF] Sodium and Potassium Salts of Mono‐and Dianionic α‐Iminopyridines

HP Nayek, N Arleth, I Trapp, M Löble… - Chemistry-a European …, 2011 - academia.edu
Hari Pada Nayek,[a, b] Nicholas Arleth,[a] Ina Trapp,[a] Matthias Lçble,[a] Pascual OÇa-
Burgos,[a] Magdalena Kuzdrowska,[a, c] Yanhua Lan,[a] Annie K. Powell,[a] Frank …

A sterically demanding iminopyridine ligand affords redox-active complexes of aluminum (III) and gallium (III)

TW Myers, LA Berben - Inorganic chemistry, 2012 - ACS Publications
The combination of an electrophilic metal center with a redox active ligand set has the
potential to provide reactivity unique from transition metal redox chemistry. In this report …

Variations in the coordination environment of Co2+, Cu2+ and Zn2+ complexes prepared from a tridentate (imino) pyridine ligand and their structural comparisons

RN Davis, JM Tanski, JC Adrian Jr, LA Tyler - Inorganica chimica acta, 2007 - Elsevier
The variations in the coordination environment of Co (II), Cu (II) and Zn (II) complexes with
the neutral, tridentate ligand bis [1-(cyclohexylimino) ethyl] pyridine (BCIP) are reported …

Synthesis and molecular and electronic structures of reduced bis (imino) pyridine cobalt dinitrogen complexes: ligand versus metal reduction

AC Bowman, C Milsmann… - Journal of the …, 2010 - ACS Publications
Sodium amalgam reduction of the aryl-substituted bis (imino) pyridine cobalt dihalide
complexes (ArPDI) CoCl2 and (iPrBPDI) CoCl2 (ArPDI= 2, 6-(2, 6-R2-C6H3N CMe) …

Preparation and reactivity of 1, 2-bis (imino) ethylpalladium (II) complexes

B Crociani, A Mantovani, A Scrivanti - Journal of Organometallic Chemistry, 1982 - Elsevier
Abstract The 1, 2-bis (imino) ethylpalladium complex, trans−[P d CI {C (= NR)︹ CH= NR}(PP
h 3) 2](R= pC 6 H 4 OMe, DAB I) can be prepared by treatment of [Pd (PPh 3) 4] with two …

Synthesis of a bulky bis (imino) pyridine compound: a methodology for systematic variation of steric bulk and energetic implications for metalation

JE Steves, MD Kennedy, KP Chiang, WS Kassel… - Dalton …, 2009 - pubs.rsc.org
A new bis (imino) pyridine compound, 2, 6-{(2, 6-Me2-C6H3) NC (t-Bu)} 2C5H3N (6), has
been synthesized with t-butyl substituents on the imino carbon atoms. The stepwise …

Sterically demanding iminopyridine ligands

T Irrgang, S Keller, H Maisel, W Kretschmer, R Kempe - 2007 - Wiley Online Library
Two sterically demanding iminopyridine ligands,(2, 6‐diisopropylphenyl)[6‐(2, 4, 6‐
triisopropylphenyl) pyridin‐2‐ylmethylene] amine and (2, 6‐diisopropylphenyl)[6‐(2, 6 …