The radical difunctionalization of alkenes with sulfonyl bifunctional represents a powerful
and straightforward approach to access functionalized alkane derivatives. However, both the …

We disclosed a visible-light-induced alkylarylation reaction of unactivated alkenes via a
metal-free radical addition/aryl translocation cascade sequence. Distal olefinic sulfonate …

A photoredox-catalyzed alkylarylation of activated alkenes via a radical C–C bond
cleavage/Truce–Smiles rearrangement cascade is developed. The protocol features mild …

In recent decades, difunctionalization of alkenes has received considerable attention as an
efficient and straightforward way to increase molecular complexity. However, examples of …

Control of selectivity is a pivotal challenge in radical chemistry owing to the high reactivity
and instability of radical species. Herein, a switchable, base-controlled strategy toward the …

Difunctionalization of alkynes represents a powerful and straightforward approach to the
synthesis of complex molecules. However, the radical difunctionalization of alkynes …

Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of
cycloalkanol-substituted styrenes with N-acyloxyphthalimides and O-acyl oximes have been …

Direct reductive cleavage of unactivated alkyl halides to radical intermediates is challenging,
whereas activation of alkyl halides via halogen atom transfer by silyl radicals is facile. Here …

A visible-light-mediated radical allylation of primary amine-derived Katritzky salts with allylic
sulfones via C (sp3)–N bond activation is reported, furnishing the corresponding alkenes in …

Alkene difunctionalization is a very attractive tool in synthetic organic chemistry. Herein, we
disclose an operationally and practically simple method to access 2 …