Synthesis and molecular and electronic structures of reduced bis (imino) pyridine cobalt dinitrogen complexes: ligand versus metal reduction

AC Bowman, C Milsmann… - Journal of the …, 2010 - ACS Publications
Sodium amalgam reduction of the aryl-substituted bis (imino) pyridine cobalt dihalide
complexes (ArPDI) CoCl2 and (iPrBPDI) CoCl2 (ArPDI= 2, 6-(2, 6-R2-C6H3N CMe) …

Reduced N-Alkyl Substituted Bis(imino)pyridine Cobalt Complexes: Molecular and Electronic Structures for Compounds Varying by Three Oxidation States

AC Bowman, C Milsmann, E Bill, E Lobkovsky… - Inorganic …, 2010 - ACS Publications
The stepwise 1− 3 electron reduction of the N-alkyl substituted bis (imino) pyridine cobalt
dichloride complexes,(RAPDI) CoCl2, was studied where RAPDI= 2, 6-(RN CMe) …

Reversible carbon–carbon bond formation induced by oxidation and reduction at a redox-active cobalt complex

CC Hojilla Atienza, C Milsmann, SP Semproni… - Inorganic …, 2013 - ACS Publications
The electronic structure of the diamagnetic pyridine imine enamide cobalt dinitrogen
complex,(iPrPIEA) CoN2 (iPrPIEA= 2-(2, 6-iPr2–C6H3N CMe)-6-(2, 6-iPr2–C6H3NC …

Electronic structure of bis (imino) pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study

SC Bart, K Chłopek, E Bill, MW Bouwkamp… - Journal of the …, 2006 - ACS Publications
The electronic structure of a family of bis (imino) pyridine iron dihalide, monohalide, and
neutral ligand compounds has been investigated by spectroscopic and computational …

Electronic effects in 4-substituted bis (imino) pyridines and the corresponding reduced iron compounds

JM Darmon, ZR Turner, E Lobkovsky, PJ Chirik - Organometallics, 2012 - ACS Publications
A family of 4-substituted bis (imino) pyridines, 4-X-iPrPDI (4-X-iPrPDI= 2, 6-(2, 6-iPr2-
C6H3N CMe) 2-4-X-C5H2N; X= CF3, tBu, Bn, NMe2), has been synthesized and the iron …

Bis (imino) pyridine iron dinitrogen compounds revisited: differences in electronic structure between four-and five-coordinate derivatives.

SCE Stieber, C Milsmann, JM Hoyt, ZR Turner… - Inorganic …, 2012 - ACS Publications
The electronic structures of the four-and five-coordinate aryl-substituted bis (imino) pyridine
iron dinitrogen complexes,(iPrPDI) FeN2 and (iPrPDI) Fe (N2) 2 (iPrPDI= 2, 6-(2, 6-iPr2 …

Oxidation and reduction of bis (imino) pyridine iron dinitrogen complexes: evidence for formation of a chelate trianion.

AM Tondreau, SCE Stieber, C Milsmann… - Inorganic …, 2013 - ACS Publications
Oxidation and reduction of the bis (imino) pyridine iron dinitrogen compound,(iPrPDI) FeN2
(iPrPDI= 2, 6-(2, 6-iPr2–C6H3–N CMe) 2C5H3N) has been examined to determine …

Neutral-ligand complexes of bis (imino) pyridine iron: Synthesis, structure, and spectroscopy

SC Bart, E Lobkovsky, E Bill, K Wieghardt… - Inorganic …, 2007 - ACS Publications
A family of bis (imino) pyridine iron neutral-ligand derivatives,(iPrPDI) FeL n (iPrPDI= 2, 6-(2,
6-iPr2− C6H3N CMe) 2C6H3N), has been synthesized from the corresponding bis …

Reduction Chemistry of Aryl- and Alkyl-Substituted Bis(imino)pyridine Iron Dihalide Compounds: Molecular and Electronic Structures of [(PDI)2Fe] Derivatives

BM Wile, RJ Trovitch, SC Bart, AM Tondreau… - Inorganic …, 2009 - ACS Publications
Sodium amalgam reduction of the aryl-substituted bis (imino) pyridine iron dibromide
complex,(EtPDI) FeBr2 (EtPDI= 2, 6-(2, 6-Et2-C6H3N CMe) 2C5H3N), under a dinitrogen …

Oxidation and reduction of bis (imino) pyridine iron dicarbonyl complexes

AM Tondreau, C Milsmann, E Lobkovsky… - Inorganic …, 2011 - ACS Publications
The oxidation and reduction of a redox-active aryl-substituted bis (imino) pyridine iron
dicarbonyl has been explored to determine whether electron-transfer events are ligand-or …