Walter Hieber s seminal work on metal carbonyl compounds not only established these
complexes as one of the most important classes of organometallics, but also disclosed …

Free borylenes are elusive, highly reactive species that are not accessible under ambient
conditions but can be generated and effectively stabilized in the coordination sphere of …

Transition-metal carbonyl complexes constitute one of the most prominent classes of
organometallic compounds, displaying a wealth of structural complexity and chemical …

Borylenes (BÀR) are highly reactive species that have only been observed at low
temperatures [1] or their presence inferred from the products of trapping reactions.[2] The …

The chemistry of borylene complexes has significantly developed over the past few years,[1]
and based on a more detailed understanding of the bonding situation of BR ligands, it is well …

N-Heterocyclic carbenes (NHCs) are effective at stabilizing unusual bonding patterns on
boron.[1, 2] Rare boron-based reactive intermediates including NHC-boryl radicals,[3] boryl …

The recent development of the photochemical transfer of borylene ligands from chromium
and tungsten borylene complexes to inorganic,[1] and more recently, organic [2] substrates …

More and more metal complexes with terminal borylene ligands will be synthesized.
Although these ligands in metal complexes must be stabilized either by integration of the …

The borylene–carbonyl moiety in [bis (silylene) B (CO)][WBr (CO) 5] shows diverse reactivity.
Reduction, migration, and complete cleavage of CO have been observed at the boron …

Experimental studies on derivatives of I and II revealed electronic interaction between the π
electrons of the carbon backbone with the empty pz orbital of the boron atom.[1, 3] As a …