Exciton coupling of merocyanine dyes from H-to J-type in the solid state by crystal engineering

A Liess, A Lv, A Arjona-Esteban, D Bialas… - Nano …, 2017 - ACS Publications
A key issue for the application of π-conjugated organic molecules as thin film solid-state
materials is the packing structure, which drastically affects optical and electronic properties …

Essential states model for merocyanine dye stacks: bridging electronic and optical absorption properties

D Bialas, C Zhong, F Wurthner… - The Journal of Physical …, 2019 - ACS Publications
An extension of the essential states model is developed to investigate the absorption and
electronic properties of a highly dipolar merocyanine dye and double and quadruple π …

Defined merocyanine dye stacks from a dimer up to an octamer by spacer-encoded self-assembly approach

E Kirchner, D Bialas, F Fennel, M Grüne… - Journal of the …, 2019 - ACS Publications
A series of well-defined chromophore stacks is obtained upon self-assembly of merocyanine
and bis (merocyanine) dyes in nonpolar solvents. Careful design of the spacer moieties …

[HTML][HTML] Structural and quantum chemical analysis of exciton coupling in homo-and heteroaggregate stacks of merocyanines

D Bialas, A Zitzler-Kunkel, E Kirchner, D Schmidt… - Nature …, 2016 - nature.com
Exciton coupling is of fundamental importance and determines functional properties of
organic dyes in (opto-) electronic and photovoltaic devices. Here we show that strong …

[HTML][HTML] Switching resonance character within merocyanine stacks and its impact on excited-state dynamics

T Kim, S Kang, E Kirchner, D Bialas, W Kim, F Würthner… - Chem, 2021 - cell.com
In this study, the optical properties and excited-state dynamics of the unique self-assembled
donor-acceptor (DA) merocyanine dye stacks from dimer up to octamer, prepared via dipole …

Linear and Nonlinear Optical Properties of Tricyanopropylidene‐Based Merocyanine Dyes: Synergistic Experimental and Theoretical Investigations

V Parthasarathy, R Pandey, PK Das, F Castet… - …, 2018 - Wiley Online Library
New merocyanines dyes with tricyanopropylidene‐based acceptor units connected to
dihexylaminophenyl or dihexylaminothiophenyl donor moieties through polyenic bridges of …

Enhanced photocurrent generation by folding-driven H-aggregate formation

A Zitzler-Kunkel, MR Lenze, K Meerholz… - Chemical Science, 2013 - pubs.rsc.org
A novel bis (merocyanine) dye has been synthesized and its folding and aggregation
behavior has been elucidated in dependence on the solvent polarity. Extended cofacially π …

[HTML][HTML] Folding and fluorescence enhancement with strong odd–even effect for a series of merocyanine dye oligomers

X Hu, A Schulz, JO Lindner, M Grüne, D Bialas… - Chemical …, 2021 - pubs.rsc.org
A series of merocyanine (MC) oligomers with a varying number of chromophores from two to
six has been synthesized via a peptide synthesis strategy. Solvent-dependent UV/vis …

Dipole–dipole interaction driven self-assembly of merocyanine dyes: from dimers to nanoscale objects and supramolecular materials

F Würthner - Accounts of chemical research, 2016 - ACS Publications
Conspectus π-Conjugation between heterocyclic donor (D) and acceptor (A) groups via a
polymethine chain leads to dyes with dipole moments greater than 10 D. These dipole …

Ultranarrow bandwidth organic photodiodes by exchange narrowing in merocyanine H‐and J‐aggregate excitonic systems

A Liess, A Arjona‐Esteban, A Kudzus… - Advanced Functional …, 2019 - Wiley Online Library
Ultranarrowband organic photodiodes (OPDs) are demonstrated for thin film solid state
materials composed of tightly packed dipolar merocyanine dyes. For these dyes the packing …