Photo‐Catalyzed Redox‐Neutral 1, 2‐Dialkylation of Alkenes

WH Sun, JY Zou, XJ Xu, JL Wang… - … Synthesis & Catalysis, 2022 - Wiley Online Library
Difunctionalization of alkenes enables construction of complex compounds in one pot. In this
report, we presented an intermolecular, redox‐neutral three‐component …

Redox‐Neutral Dual Functionalization of Electron‐Deficient Alkenes

F Pettersson, G Bergonzini, C Cassani… - … –A European Journal, 2017 - Wiley Online Library
Visible‐light photoredox catalysis has been utilized in a new multicomponent reaction
forming β‐functionalized δ‐diketones under mild conditions in an operationally convenient …

Photoredox deoxygenative allylation of carboxylic acids via selective 1, 6-addition of acyl radicals to electron-deficient 1, 3-dienes

L Zhang, Y Li, Z Guo, Y Li, N Li, W Li, C Zhu… - Chinese Journal of …, 2023 - Elsevier
Abstract We report the 1, 6-addition of acyl radicals to the electron-deficient 1, 3-dienes
under visible-light photoredox catalysis. The deoxygenative allylation of the carboxylic acid …

Photoredox-catalyzed 1, 2-oxo-alkylation of vinyl arenes with 1, 3-diketones: an approach to 1, 4-dicarbonyls via C–C activation

P Palani, A Arumugam, D Raja, K Muthu… - Chemical …, 2023 - pubs.rsc.org
A mild and inexpensive approach to synthesising a series of 1, 4-diketones in moderate to
excellent yields via 1, 2-oxo alkylation has been developed using fluorescein as a …

Visible-Light Photoredox-Catalyzed Divergent 1, 2-Diacylation and Hydroacylation of Alkenes with Carboxylic Acid Anhydride

Y Zhou, L Zhao, M Hu, XH Duan, L Liu - Organic Letters, 2023 - ACS Publications
A photoredox-catalyzed divergent 1, 2-dicarbonylation and hydroacylation of alkenes with
acid anhydride is presented. This approach offers a mild and efficient entry to 1, 4-dicarbonyl …

Recent Advances in Photoredox-Catalyzed Difunctionalization of Alkenes

Y Liu, H Liu, X Liu, Z Chen - Catalysts, 2023 - mdpi.com
Alkenes and their related analogs are ideal starting materials for organic synthesis, and the
selective difunctionalization of alkenes, which allows the simultaneous introduction of two …

Photoredox-catalyzed alkylarylation of activated alkenes via a ring-opening/Truce–Smiles rearrangement cascade

JH Zhang, HJ Miao, H Xin, G Wang, X Yang… - Chemical …, 2024 - pubs.rsc.org
A photoredox-catalyzed alkylarylation of activated alkenes via a radical C–C bond
cleavage/Truce–Smiles rearrangement cascade is developed. The protocol features mild …

Photocatalytic radical aroylation of unactivated alkenes: pathway to β-functionalized 1, 4-, 1, 6-, and 1, 7-diketones

S Sarkar, A Banerjee, W Yao, EV Patterson… - ACS catalysis, 2019 - ACS Publications
We report the development of a photocatalytic strategy for the synthesis of β-functionalized
unsymmetrical 1, 4-, 1, 6-, and 1, 7-diketones from aroyl chlorides and unactivated alkenes …

Electrophotocatalytic Reductive 1, 2‐Diarylation of Alkenes with Aryl Halides and Cyanoaromatics

L Zeng, JH Qin, GF Lv, M Hu, Q Sun… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary The radical‐mediated reductive functionalization of aryl halides
has been extensively studied. However, the related radical‐mediated intermolecular …

Photocatalytic annulation–alkynyl migration strategy for multiple functionalization of dual unactivated alkenes

Q Zhao, WJ Hao, HN Shi, T Xu, SJ Tu, B Jiang - Organic letters, 2019 - ACS Publications
A novel photoredox catalysis for multiple functionalization of two different types of
unactivated alkenes in a single operation was reported through a conceptually new mode of …