The construction of aromatic compounds from non-aromatic compounds via skeletal editing
is appealing yet challenging in organic chemistry. Herein, we report an approach for the …

Radical difunctionalization of aliphatic alkynes provides direct access to valuable multi‐
substituted alkenes, but achieving a high level of chemo‐and stereo‐control remains a …

Reactions that lead to destruction of aromatic ring systems often require harsh conditions
and, thus, take place with poor selectivities. Selective partial dearomatization of fused …

Efficient and modular synthesis of structurally diverse 1, 4-diketones from readily available
building blocks represents an essential but challenging task in organic chemistry. Herein …

Divergent synthesis is a powerful strategy for the fast assembly of different molecular
scaffolds from identical starting materials. We describe here a solvent-controlled …

In view of the widespread significance of amide functional groups in organic synthesis and
pharmaceutical studies, an efficient and practical synthetic protocol that avoids the use of …

Alkenes serve as versatile building blocks in diverse organic transformations. Despite
notable advancements in olefination methods, a general strategy for the direct conversion of …

Abstract The catalytic C (sp3)− C (sp3) coupling of alkyl halides and tertiary amines offers a
promising tool for the rapid decoration of amine skeletons. However, this approach has not …

Under mild blue-light irradiation, α-acylated saturated heterocycles undergo a
photomediated one-atom ring contraction that extrudes a heteroatom from the cyclic core …

We developed a simple and convenient method to assemble biaryls exploiting a photoredox
catalyst and visible light. Diazonium salts generate aryl radicals that could then add on …