Doping by design: enhanced thermoelectric performance of GeSe alloys through metavalent bonding

Y Yu, C Zhou, T Ghosh, CF Schön, Y Zhou… - Advanced …, 2023 - Wiley Online Library
Doping is usually the first step to tailor thermoelectrics. It enables precise control of the
charge‐carrier concentration and concomitant transport properties. Doping should also turn …

[PDF][PDF] Two-step phase manipulation by tailoring chemical bonds results in high-performance GeSe thermoelectrics

W Yao, Y Zhang, T Lyu, W Huang, N Huang, X Li… - The Innovation, 2023 - cell.com
In thermoelectrics, phase engineering serves a crucial function in determining the power
factor by affecting the band degeneracy. However, for low-symmetry compounds, the …

Thermoelectric Performance of IV–VI Compounds with Octahedral‐Like Coordination: A Chemical‐Bonding Perspective

M Cagnoni, D Führen, M Wuttig - Advanced materials, 2018 - Wiley Online Library
Thermoelectric materials provide a challenge for materials design, since they require
optimization of apparently conflicting properties. The resulting complexity has favored trial …

In situ design of high‐performance dual‐phase GeSe thermoelectrics by tailoring chemical bonds

L Hu, B Duan, T Lyu, N Lin, C Zhang… - Advanced Functional …, 2023 - Wiley Online Library
Composite engineering favors high thermoelectric performance by tuning the carrier and
phonon transport. Herein, orthorhombic and rhombohedral dual‐phase GeSe are designed …

Metavalent bonding in GeSe leads to high thermoelectric performance

D Sarkar, S Roychowdhury, R Arora… - Angewandte Chemie …, 2021 - Wiley Online Library
Orthorhombic GeSe is a promising thermoelectric material. However, large band gap and
strong covalent bonding result in a low thermoelectric figure of merit, zT≈ 0.2. Here, we …

[HTML][HTML] Thermoelectric properties of GeSe

X Zhang, J Shen, S Lin, J Li, Z Chen, W Li, Y Pei - Journal of Materiomics, 2016 - Elsevier
The recently reported superior thermoelectric performance of SnSe, motivates the current
work on the thermoelectric properties of polycrystalline GeSe, an analog compound with the …

Germanium chalcogenide thermoelectrics: electronic structure modulation and low lattice thermal conductivity

S Roychowdhury, M Samanta, S Perumal… - Chemistry of …, 2018 - ACS Publications
Thermoelectric materials can convert untapped heat to electricity and are expected to have
an important role in future energy utilization. IV–VI metal chalcogenides are the most …

High Thermoelectric Performance of New Rhombohedral Phase of GeSe stabilized through Alloying with AgSbSe2

Z Huang, SA Miller, B Ge, M Yan… - Angewandte Chemie …, 2017 - Wiley Online Library
GeSe is a IV–VI semiconductor, like the excellent thermoelectric materials PbTe and SnSe.
Orthorhombic GeSe has been predicted theoretically to have good thermoelectric …

Effective enhancement of thermoelectric and mechanical properties of germanium telluride via rhenium-doping

A Suwardi, SH Lim, Y Zheng, X Wang… - Journal of Materials …, 2020 - pubs.rsc.org
GeTe as one of the most promising medium temperature thermoelectrics has progressed
leaps and bounds in recent years, largely thanks to a combination of its unique electronic …

Chemical Insights into PbSe–x%HgSe: High Power Factor and Improved Thermoelectric Performance by Alloying with Discordant Atoms

JM Hodges, S Hao, JA Grovogui, X Zhang… - Journal of the …, 2018 - ACS Publications
Thermoelectric generators can convert heat directly into usable electric power but suffer from
low efficiencies and high costs, which have hindered wide-scale applications. Accordingly …