Silica particles convert thiol-containing molecules to disulfides

Y Li, KW Kolasinski, RN Zare - Proceedings of the National …, 2023 - National Acad Sciences
Synthetic amorphous silica is a common food additive and a popular cosmetic ingredient.
Mesoporous silica particles are also widely studied for their potential use in drug delivery …

A Kinetic Study of the Reactions of Sulfate Radicals at the Silica Nanoparticle− Water Interface

P Caregnato, VC Mora, GC Le Roux… - The Journal of …, 2003 - ACS Publications
Sulfate radicals, SO4•-, were generated using flash photolysis of aqueous S2O82-solutions
and the reactions of the inorganic radicals with the surface of suspended silica nanoparticles …

Toxicity of silica nanomaterials: zeolites, mesoporous silica, and amorphous silica nanoparticles

A Petushkov, N Ndiege, AK Salem… - Advances in Molecular …, 2010 - Elsevier
Publisher Summary In this chapter, an overview of the toxicity of silica-based nanomaterials
is presented. Porous materials, such as crystalline, microporous zeolites, and mesoporous …

Processing pathway dependence of amorphous silica nanoparticle toxicity: colloidal vs pyrolytic

H Zhang, DR Dunphy, X Jiang, H Meng… - Journal of the …, 2012 - ACS Publications
We have developed structure/toxicity relationships for amorphous silica nanoparticles (NPs)
synthesized through low-temperature colloidal (eg, Stöber silica) or high-temperature …

Introduction of disulfide bridges within silica nanoparticles to control their intra-cellular degradation

S Quignard, S Masse, G Laurent… - Chemical …, 2013 - pubs.rsc.org
Introduction of disulfide bridges within silica nanoparticles to control their intra-cellular
degradation - Chemical Communications (RSC Publishing) DOI:10.1039/C3CC41062E Royal …

Does vitreous silica contradict the toxicity of the crystalline silica paradigm?

M Ghiazza, M Polimeni, I Fenoglio… - Chemical Research …, 2010 - ACS Publications
“Vitreous silica” is a particular form of amorphous silica, much neglected in experimental
studies on silica toxicity. In spite of the incorrect term “quartz glass”, often employed, this …

Supramolecular complex antioxidant consisting of vitamins C, E and hydrophilic–hydrophobic silica nanoparticles

IV Laguta, PO Kuzema, ON Stavinskaya… - … Physics, Chemistry, and …, 2010 - Springer
Samples with varied amount of surface trimethylsilyl groups were obtained via gas-phase
chemical modification of silica nanoparticles. The biocompatibility tests conducted in …

Physicochemical determinants in the cellular responses to nanostructured amorphous silicas

E Gazzano, M Ghiazza, M Polimeni, V Bolis… - Toxicological …, 2012 - academic.oup.com
Amorphous silicas, opposite to crystalline polymorphs, have been regarded so far as
nonpathogenic, but few studies have addressed the toxicity of the wide array of amorphous …

Mechanism of hydroxyl radical generation from a silica surface: molecular orbital calculations

J Narayanasamy, JD Kubicki - The Journal of Physical Chemistry …, 2005 - ACS Publications
The interaction of an H2O molecule with cluster models of fractured silica surfaces was
studied by means of quantum mechanical calculations. Two clusters representing homolytic …

[HTML][HTML] The toxicological mode of action and the safety of synthetic amorphous silica—A nanostructured material

C Fruijtier-Pölloth - Toxicology, 2012 - Elsevier
Synthetic amorphous silica (SAS), in the form of pyrogenic (fumed), precipitated, gel or
colloidal SAS, has been used in a wide variety of industrial and consumer applications …