Molecular brushes with spontaneous gradient by atom transfer radical polymerization

H Lee, K Matyjaszewski, S Yu, SS Sheiko - Macromolecules, 2005 - ACS Publications
Spontaneous gradient copolymers were synthesized by atom transfer radical polymerization
(ATRP) of acrylates and methacrylates and were subsequently employed to prepare …

Synthesis of molecular brushes with gradient in grafting density by atom transfer polymerization

HG Börner, D Duran, K Matyjaszewski… - …, 2002 - ACS Publications
Macromolecular brushes with a gradient of side-chain spacing along the backbone have
been synthesized by the “grafting from” approach using atom transfer radical polymerization …

Synthesis of molecular brushes with gradient in grafting density by atom transfer polymerization

HG Borner, D Duran, K Matyjaszewski, M Da Silva… - …, 2002 - hero.epa.gov
Macromolecular brushes with a gradient of side-chain spacing along the backbone have
been synthesized by the" grafting from" approach using atom transfer radical polymerization …

Initiation efficiency in the synthesis of molecular brushes by grafting from via atom transfer radical polymerization

BS Sumerlin, D Neugebauer, K Matyjaszewski - Macromolecules, 2005 - ACS Publications
Grafting from via atom transfer radical polymerization (ATRP) was employed for the
synthesis of densely grafted molecular brushes. A poly (2-(2-bromopropionyl) oxyethyl …

Architecture of prototype copolymer brushes by grafting-from ATRP approach from functionalized alternating comb-shaped copolymers

K Ishizu, H Yamada - Macromolecules, 2007 - ACS Publications
Atom transfer radical polymerization (ATRP) was applied to a novel synthesis of prototype
copolymer brushes. The procedure included the following steps:(1) free-radical …

Novel brush copolymers via controlled radical polymerization

R Venkatesh, L Yajjou, CE Koning… - … chemistry and physics, 2004 - Wiley Online Library
A combination of reversible addition‐fragmentation chain transfer (RAFT) polymerization
and atom transfer radical polymerization (ATRP) techniques were applied for the synthesis …

Synthesis of amphiphilic copolymer brushes possessing alternating poly(methyl methacrylate) and poly(N‐isopropylacrylamide) grafts via a combination of ATRP and …

J Yin, Z Ge, H Liu, S Liu - Journal of Polymer Science Part A …, 2009 - Wiley Online Library
We report on the synthesis of well‐defined amphiphilic copolymer brushes possessing
alternating poly (methyl methacrylate) and poly (N‐isopropylacrylamide) grafts, poly (PMMA …

Synthesis of molecular brushes with block copolymer side chains using atom transfer radical polymerization

HG Börner, K Beers, K Matyjaszewski, SS Sheiko… - …, 2001 - ACS Publications
Brush macromolecules having poly (n-butyl acrylate-block-styrene) and poly (styrene-block-
n-butyl acrylate) side chains have been synthesized by the “grafting from” approach using …

Amphiphilic cylindrical core− shell brushes via a “grafting from” process using ATRP

G Cheng, A Böker, M Zhang, G Krausch… - …, 2001 - ACS Publications
Atom transfer radical polymerization (ATRP) was applied to the synthesis of amphiphilic
cylindrical polymer brushes by using the “grafting from” technique. The procedure included …

Synthesis of amphiphilic copolymer brushes: Poly (ethylene oxide)‐graft‐polystyrene

Z Li, P Li, J Huang - Journal of Polymer Science Part A …, 2006 - Wiley Online Library
A well‐defined amphiphilic copolymer brush with poly (ethylene oxide) as the main chain
and polystyrene as the side chain was successfully prepared by a combination of anionic …