Hydroarylation of alkenes has been demonstrated to be an atom-economic approach to
access functionalized arenes from easily accessible raw materials. Herein, we report a …

Intramolecular hydroarylation of alkenes through hydrogen atom transfer (HAT) represents a
robust method to prepare benzo-fused heterocycles. However, the reported methods have …

β-(Hetero) arylethylamines are privileged structural motifs found in many high-value organic
molecules, including pharmaceuticals and natural products. To construct these important …

Photoredox catalysis is a powerful means to generate odd-electron species under mild
reaction conditions from a wide array of radical precursors. Herein, we present the …

A catalyst-free approach for the multicomponent aminoheteroarylation reaction of alkenes
with N-aminopyridinium salts and heteroarenes is herein described. The reaction shows …

Radical difunctionalization of aliphatic alkynes provides direct access to valuable multi‐
substituted alkenes, but achieving a high level of chemo‐and stereo‐control remains a …

Substituted alkenes are pivotal structural motifs found in pharmaceuticals and
agrochemicals. Although numerous methods have been developed to construct substituted …

Alkene aminoarylation with arylsulfonylacetamides via a visible light-mediated radical
Smiles–Truce rearrangement represents a convenient approach to the privileged …

Catalytic, intermolecular hydroaminoalkylation (HAA) of styrenes provides a powerful
disconnection for pharmacologically relevant γ-arylamines, but current methods cannot …

Dearomatization of indole derivatives offers a straightforward approach to access diverse
indolines. To date, the corresponding dearomative transformations involving electron …