Visible‐light‐induced dearomatizations

M Okumura, D Sarlah - European journal of organic chemistry, 2020 - Wiley Online Library
The dearomatization of aromatic compounds is an important synthetic strategy used in
accessing complex three‐dimensional structures from simple aromatic precursors. This …

Visible-light induced dearomatization reactions

YZ Cheng, Z Feng, X Zhang, SL You - Chemical Society Reviews, 2022 - pubs.rsc.org
Dearomatization reactions provide rapid access to structurally complex three-dimensional
molecules from simple aromatic compounds. Plenty of reports have demonstrated their …

Visible-light induced divergent dearomatization of indole derivatives: controlled access to cyclobutane-fused polycycles and 2-substituted indolines

W Zhuang, YZ Cheng, XL Huang, Q Huang… - Organic Chemistry …, 2021 - pubs.rsc.org
A photocatalytic protocol for the divergent dearomative functionalization of indole derivatives
is reported. Under the irradiation of visible light, either dimerization or reduction occurs …

Recent advances in the dearomative functionalisation of heteroarenes

N Kratena, B Marinic, TJ Donohoe - Chemical Science, 2022 - pubs.rsc.org
Dearomatisation reactions of (hetero) arenes have been widely employed as efficient
methods to obtain highly substituted saturated cyclic compounds for over a century. In recent …

Shaping molecular landscapes: recent advances, opportunities, and challenges in dearomatization

CJ Huck, D Sarlah - Chem, 2020 - cell.com
Dearomatization is a fundamental chemical transformation, and it underlies some of the
most efficient tactics for generating three-dimensional complexity from basic two …

Visible-light-induced intermolecular dearomative cyclization of 2-bromo-1, 3-dicarbonyl compounds and alkynes: Synthesis of spiro [4.5] deca-1, 6, 9-trien-8-ones

W Dong, Y Yuan, X Gao, M Keranmu, W Li, X Xie… - Organic …, 2018 - ACS Publications
A visible-light-induced photocatalytic intermolecular dearomative cyclization of 2-bromo-1, 3-
dicarbonyl compounds and alkynes afforded biologically important spirocarbocycle …

Synthesis of complex bicyclic scaffolds by intermolecular photosensitized dearomative cycloadditions of activated alkenes and naphthalenes

W Wang, Y Cai, R Guo, MK Brown - Chemical Science, 2022 - pubs.rsc.org
The rapid buildup of molecular complexity from simple precursors is a key goal in organic
chemistry. One strategy to achieve this is through a dearomative cycloaddition wherein a 2D …

Selective skeletal editing of polycyclic arenes using organophotoredox dearomative functionalization

P Ji, CC Davies, F Gao, J Chen, X Meng… - Nature …, 2022 - nature.com
Reactions that lead to destruction of aromatic ring systems often require harsh conditions
and, thus, take place with poor selectivities. Selective partial dearomatization of fused …

Rejuvenation of dearomative cycloaddition reactions via visible light energy transfer catalysis

A Palai, P Rai, B Maji - Chemical Science, 2023 - pubs.rsc.org
Dearomative cycloaddition is a powerful technique to access sp3-rich three-dimensional
structural motifs from simple flat, aromatic feedstock. The building-up of unprecedentedly …

Intermolecular Dearomatization of Naphthalene Derivatives by Photoredox‐Catalyzed 1, 2‐Hydroalkylation

YZ Cheng, XL Huang, WH Zhuang… - Angewandte …, 2020 - Wiley Online Library
An intermolecular hydroalkylative dearomatization of naphthalenes with commercially
available α‐amino acids is achieved via visible‐light photoredox catalysis. With an organic …