Optimization of reaction parameters by using response surface methodology (RSM) for the selective dehydration of glucose to 5-hydroxymethylfurfural (5-HMF), a …

R Tomer, P Biswas - Catalysis Today, 2022 - Elsevier
A highly active and selective mesoporous TiO 2 was developed by the sol-gel hydrolysis
technique for the selective transformation of glucose to 5-hydroxymethylfurfural (5-HMF) …

Reaction kinetics study and the estimation of thermodynamic parameters for the conversion of glucose to 5-hydroxymethylfurfural (5-HMF) in a dimethyl sulfoxide …

R Tomer, P Biswas - Journal of the Taiwan Institute of Chemical Engineers, 2022 - Elsevier
Backgrounds Glucose is a potential feedstock for the production of 5-HMF, a top ten platform
chemical. The kinetics of glucose conversion to 5-HMF in organic dimethylsulfoxide (DMSO) …

Dehydration of glucose/fructose to 5-hydroxymethylfurfural (5-HMF) over an easily recyclable sulfated titania (SO 4 2−/TiO 2) catalyst

R Tomer, P Biswas - New Journal of Chemistry, 2020 - pubs.rsc.org
A new SO42−/TiO2 catalyst was developed via sol–gel hydrolysis followed by the wetness
impregnation method. The Lewis (L) and Brønsted (B) site proportion in the catalyst was …

One-pot conversion of glucose to 5-hydroxymethylfurfural under aqueous conditions using acid/base bifunctional mesoporous silica catalyst

A Modak, AR Mankar, RR Sonde, KK Pant - Renewable Energy, 2023 - Elsevier
One-pot conversion of carbohydrate-derived biomass compounds to 5-hydroxymethylfurfural
(HMF) using an environmentally green solvent such as water is meritorious, yet challenging …

Efficient production of 5-hydroxymethylfurfural from glucose over silica-tin oxide composite catalysts

T Zhang, H Wei, R Ling, Y Jin, H Xiao, W Li… - Microporous and …, 2021 - Elsevier
In this study, silica-tin oxide composites (xSiSnO) and a H 3 PO 4 modified 20SiSnO
(SiSnPO) have been synthesized via a simple procedure and evaluated for the catalytic …

Trade-Off between Acidic Sites and Crystallinity of the WO3–TiO2 Catalyst toward Dehydration of Glucose to 5-Hydroxymethylfurfural

P Ganji, S Roy - Energy & Fuels, 2019 - ACS Publications
The dehydration of glucose to 5-hydroxymethylfurfural (HMF) is one of the most coveted
catalytic reactions from energy and environmental perspective. In spite of the exhaustive …

Halloysite-supported silicotungstic acid as an efficient catalyst for dehydration of fructose to 5-hydroxymethylfurfural

F Saghandali, M Kazemeini, S Sadjadi - … of Physics and Chemistry of Solids, 2024 - Elsevier
Three Keggin-type heteropolyacids were impregnated upon halloysite to produce
heterogeneous acidic catalysts for synthesizing 5-hydroxymethylfurfural (5-HMF) …

Design of sulfonated mesoporous silica catalyst for fructose dehydration guided by difructose anhydride intermediate incorporated reaction network

Y Huang, PY Chao, TY Cheng, Y Ho, CT Lin… - Chemical Engineering …, 2016 - Elsevier
A reaction network consisting of dimerization, dehydration and isomerization of fructose for
the synthesis of 5-hydroxymethylfurfural (HMF) is devised. Difructose anhydride (DFA) …

Catalytic behaviour of TiO 2–ZrO 2 binary oxide synthesized by sol–gel process for glucose conversion to 5-hydroxymethylfurfural

L Atanda, A Silahua, S Mukundan, A Shrotri… - RSC …, 2015 - pubs.rsc.org
The catalytic application of as-synthesized TiO2–ZrO2 binary oxides was examined for the
conversion of glucose to produce 5-hydroxymethylfurfural (HMF). Highest HMF yield (74%) …

Syntheses of 5-Hydroxymethylfurfural Through Glucose Dehydration in Diphasic Solvent System on ZrO2 and SO42−/TiO2-SiO2 Catalyst

Y Wang, Y Liu, L Yang, R Ruan, P Wen… - Synthesis and Reactivity …, 2016 - Taylor & Francis
Synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose in water-dimethyl sulfoxide
diphasic system using solid base ZrO2 and SO42−/TiO2-SiO2 catalysts was studied. The …