The ability of gold nanoparticles (AuNPs) to catalyze reactions involving radicals is poorly studied. However, AuNPs are used in applications where chemical reactions involving …
Methyl-peroxyl radicals react with Au0 and Ag0 nanoparticles (NPs) in aqueous suspensions in fast reaction with rate constants which approach the diffusion-controlled limit …
J Chang, RD Taylor, RA Davidson… - The Journal of …, 2016 - ACS Publications
Nanomaterials can enhance the effect of X-rays, but the mechanisms of enhancement can be complicated. Electron paramagnetic resonance (EPR) was used here to shed light on …
MS Ide, RJ Davis - Accounts of chemical research, 2014 - ACS Publications
Although gold is generally considered to be a relatively inert metal, supported gold nanoparticles have demonstrated exceptionally high catalytic activity for the oxidation of …
N Li, X Liu - ChemistrySelect, 2019 - Wiley Online Library
A facile approach for dendrimer stabilized gold nanoparticles and their application in the generation of hydroxyl radicals has been developed. Dendrimer stabilized AuNP‐1 exhibits …
Z Zhang, A Berg, H Levanon… - Journal of the …, 2003 - ACS Publications
Electron paramagnetic resonance (EPR) spectroscopy was used to study the interactions between stable free radicals and gold nanoparticles. The nitroxyl free radicals used were …
P Savchenko, D Zelikovich, H Elgavi Sinai… - Journal of the …, 2024 - ACS Publications
Engineered metallic nanoparticles, which are found in numerous applications, are usually stabilized by organic ligands influencing their interfacial properties. We found that the …
Enhanced acyl radical formation in the Au nanoparticle -catalysed aldehyde oxidation - Chemical Communications (RSC Publishing) DOI:10.1039/B918200D Royal Society of …
L Hu, X Cao, J Yang, M Li, H Hong, Q Xu… - Chemical …, 2011 - pubs.rsc.org
Ultra-thin gold nanowires (GNWs), with uniform surface crystallinity, appear much more active than gold nanoclusters in benzylic compound oxidation. Ethylbenzene oxidation was …