Indoles are heterocyclic motifs that are embedded in a large number of bioactive natural
products and pharmaceuticals.[1] As such, the search for sustainable and more efficient …

We report the application of visible-light photoredox catalysis for the formation of C− C
bonds between tertiary N-arylamines and nitroalkanes via an oxidative aza-Henry reaction …

Although the use of photons as reagents has enjoyed an incredibly rich history,[1] the use of
photons of red-shifted wavelengths, particularly those extending into what is known as the …

The photocatalytic preparation of aminoalkylated heteroarenes from haloalkylamides via a
1, 4‐aryl migration from nitrogen to carbon, conceptually analogous to a radical Smiles …

Quinones exhibit orthogonal ground‐and excited‐state reactivities and are therefore highly
suitable organocatalysts for the development of sequential catalytic processes. Herein, the …

Conspectus Single electron oxidation of amines provides an efficient way to access
synthetically useful α-aminoalkyl radicals as reactive intermediates. After the single electron …

We introduce here a two-component annulation strategy that provides access to a diverse
collection of five-and six-membered saturated heterocycles from aryl alkenes and a family of …

During the past decade, visible light photocatalysis has become a powerful synthetic
platform for promoting challenging bond constructions under mild reaction conditions. These …

Visible light induced photoredox catalysis is an efficient method for radical activation.
Herein, we report the photoredox catalysis involving an intramolecular radical–radical …

Conspectus Cascade reactions represent a class of ideal organic reactions because they
empower efficiency, elegance, and novelty. However, development of cascade reactions …