Batch and flow photochemical benzannulations based on the reaction of ynamides and diazo ketones. Application to the synthesis of polycyclic aromatic and …

TP Willumstad, O Haze, XY Mak, TY Lam… - The Journal of …, 2013 - ACS Publications
Highly substituted polycyclic aromatic and heteroaromatic compounds are produced via a
two-stage tandem benzannulation/cyclization strategy. The initial benzannulation step …

Extended study of visible-light-induced photocatalytic [4+ 2] benzannulation: synthesis of polycyclic (hetero) aromatics

T Chatterjee, DS Lee, EJ Cho - The Journal of Organic Chemistry, 2017 - ACS Publications
Herein we report an extended study of [4+ 2] benzannulation reactions of 2-(hetero) aryl-
substituted anilines with alkynes by visible light photocatalysis. The method requires the use …

Benzannulation via the reaction of ynamides and vinylketenes. Application to the synthesis of highly substituted indoles

TY Lam, YP Wang, RL Danheiser - The Journal of organic …, 2013 - ACS Publications
A two-stage “tandem strategy” for the synthesis of indoles with a high level of substitution on
the six-membered ring is described. Benzannulation based on the reaction of …

[引用][C] Synthesis of heterocycles via intramolecular annulation of nitrene intermediates

BCG Soderberg - Current Organic Chemistry, 2000 - ingentaconnect.com
This article presents a comprehensive review of synthetically useful intramolecular
annulation reactions of nitrene and nitrenoid intermediates leading to heterocyclic …

Exploitation of intramolecular photochemical arylation of N-substituted enaminones. Efficient, general synthesis of heterocyclic compounds

H Iida, Y Yuasa, C Kibayashi - The Journal of Organic Chemistry, 1979 - ACS Publications
1236 J. Org. Chem., Vol. 44, No. 8, 1979 Iida, Yuasa, and Kibayashi to a powder. The
mixture was charged to a 100 mL, round-bottom flask equipped with a Dean-Stark trap and …

Photochemical intramolecular amination for the synthesis of heterocycles

S Parisien-Collette, C Cruché, X Abel-Snape… - Green chemistry, 2017 - pubs.rsc.org
Polycyclic heterocycles can be formed in good to excellent yields via photochemical
conversion of the corresponding substituted aryl azides under irradiation with purple LEDs …

Visible Light Promoted Brominative Dearomatization of Biaryl Ynones to Spirocycles

B Roy, P Kuila, D Sarkar - The Journal of Organic Chemistry, 2023 - ACS Publications
Bromine induced spiro cyclization of biaryl ynones facilitated the synthesis of spiro [5, 5]
trienones suitable for extended functionality at the C (3′) position. Herein, a step-economic …

Synthesis of highly substituted quinolines via a tandem ynamide benzannulation/iodocyclization strategy

TP Willumstad, PD Boudreau… - The Journal of Organic …, 2015 - ACS Publications
A two-stage “tandem strategy” for the regiocontrolled synthesis of very highly substituted
quinolines is described. Benzannulation based on the reaction of cyclobutenones or diazo …

Intermolecular [3+2] Annulation of Cyclopropylanilines with Alkynes, Enynes, and Diynes via Visible Light Photocatalysis

TH Nguyen, SA Morris, N Zheng - Advanced synthesis & …, 2014 - Wiley Online Library
One‐step syntheses of carbocycles substituted with amines from simple starting materials
remain rare. We recently developed an intermolecular [3+ 2] annulation of …

New approaches to ondansetron and alosetron inspire a versatile, flow photochemical method for indole synthesis

W Sun, WAT Raimbach, LD Elliott… - Chemical …, 2022 - pubs.rsc.org
New approaches to ondansetron and alosetron inspire a versatile, flow photochemical method
for indole synthesis - Chemical Communications (RSC Publishing) DOI:10.1039/D1CC05700F …