Regulation of Ge vacancies through Sm doping resulting in superior thermoelectric performance in GeTe

T Zhang, S Deng, X Zhao, X Ruan, N Qi… - Journal of Materials …, 2022 - pubs.rsc.org
A high thermoelectric figure of merit ZT of 2.5 at 730 K is achieved in p-type Ge1− xSmxTe
through synergetic optimization of electrical and thermal transport properties. Sm doping …

Vacancy Suppression Induced Synergetic Optimization of Thermoelectric Performance in Sb-Doped GeTe Evidenced by Positron Annihilation Spectroscopy

T Zhang, N Qi, X Su, X Tang… - ACS Applied Materials & …, 2023 - ACS Publications
Synergetic optimization of the electrical and thermal transport performance of GeTe has
been achieved through Sb doping in this work, resulting in a high thermoelectric figure of …

The role of Ge vacancies and Sb doping in GeTe: a comparative study of thermoelectric transport properties in SbxGe1-1.5 xTe and SbxGe1-xTe compounds

S Chen, H Bai, H Wu, J Wu, Z Chen, X Su, C Uher… - Materials Today …, 2022 - Elsevier
Optimizing the thermoelectric properties of GeTe-based compounds usually involves the
modulation of Ge vacancies and dopants. However, the mixture of vacancies and dopants …

Contrasting roles of trivalent dopants M (M= In, Sb, Bi) in enhancing the thermoelectric performance of Ge0. 94M0. 06Te

Y Jin, D Wang, Y Zhu, L Su, T Hong, Z Wang, ZH Ge… - Acta Materialia, 2023 - Elsevier
Thermoelectric materials can achieve the interconversion of electricity and heat, providing
potential for power generation. It is a challenge to elevate conversion efficiency due to the …

Boosting the thermoelectric performance of GeTe by manipulating the phase transition temperature via Sb doping

Y Jin, D Wang, Y Qiu, LD Zhao - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
It is well known that the thermoelectric performance of GeTe is difficult to manipulate due to
its intrinsic overhigh carrier concentration and phase transition. Herein, we demonstrate that …

[HTML][HTML] Condensed point defects enhance thermoelectric performance of rare-earth Lu-doped GeTe

WY Lyu, WD Liu, M Li, XL Shi, M Hong, T Cao… - Journal of Materials …, 2023 - Elsevier
Heavy rare-earth element doping can effectively strengthen phonon scattering, suppress the
lattice thermal conductivity, and enhance the overall thermoelectric performance of GeTe …

Stabilizing the optimal carrier concentration in Al/Sb-codoped GeTe for high thermoelectric performance

X Wang, W Xue, Z Zhang, X Li, L Yin… - … Applied Materials & …, 2021 - ACS Publications
GeTe is a promising thermoelectric material and has attracted growing research interest
recently. In this study, the effect of Al doping and Al&Sb codoping on the thermoelectric …

Enhanced Thermoelectric Performance in Ge0.955−xSbxTe/FeGe2 Composites Enabled by Hierarchical Defects

L Xie, R Liu, C Zhu, Z Bu, W Qiu, J Liu, F Xu, Y Pei… - Small, 2021 - Wiley Online Library
Manipulations of carrier and phonon scatterings through hierarchical structures have been
proved to be effective in improving thermoelectric performance. Previous efforts in GeTe …

High power factor and enhanced thermoelectric performance in Sc and Bi codoped GeTe: Insights into the hidden role of rhombohedral distortion degree

Z Liu, W Gao, W Zhang, N Sato… - Advanced Energy …, 2020 - Wiley Online Library
Modification of crystal symmetry induced by chemical doping or alloying is well known to
optimize the charge carrier transport properties in thermoelectric materials. Historically, the …

Bi–Zn codoping in GeTe synergistically enhances band convergence and phonon scattering for high thermoelectric performance

Z Guo, Q Zhang, H Wang, X Tan, F Shi… - Journal of Materials …, 2020 - pubs.rsc.org
As an attractive lead-free thermoelectric candidate, GeTe-based materials have been
intensively studied in recent years. However, the ZT value of pristine GeTe is limited around …