The electrolytes used in enzymatic biosensors or biofuel cells have always been considered
to be inert. However, recent studies have demonstrated that this assumption is not correct …

The purpose of a kinetic model of a biosensor is to identify the key experimental factors
(such as the rates of reactions, rates of mass transport, loading of the bio-recognition …

The range of salts used as supporting electrolytes in electrochemical studies of redox
proteins and enzymes varies widely, with the choice of an electrolyte relying on the …

The faradaic response of ferrocene–methanol when used as a mediator for the catalytic
oxidation of glucose by glucose oxidase was examined in a range of electrolytes. The …

The use of electrochemical methods to study protein and enzyme electron transfer reaction
kinetics, thermodynamics, and mechanisms directly with electrodes is becoming a mature …

Electrochemistry of Redox Enzymes Page 1 2 Electrochemistry of Redox Enzymes James F.
Rusling,†,z Bingquan Wang†,à and Sei-eok Yun†,x †Department of Chemistry (U-60), à…

We introduce electrochemistry of redox proteins and enzymes in the context of functional
studies. We explain the fundamental concepts of electrochemistry only as far as they are …

The Study of the electron-transfer process between the redox proteins and electrodes is not
only valuabe in providing information to understand the metabolic process, but also is the …

As a consequence of their subtle molecular architecture, proteins show great selectivity and
specificity in their interactions with other molecules. Such interactions play an integral part in …

Continuous electric fields (E) modify the transport flows and the intramembrane
concentration profiles of protons or of ionic substrates or cofactors (inhibitors). These …