In recent years, earth-abundant transition metal catalysts have been used to make great
achievements on homogenous catalysis, including the field of enantioselective …

Conspectus Transition metal catalyzed asymmetric hydrofunctionalization of readily
available unsaturated hydrocarbons presents one of the most straightforward and atom …

Stereogenic carbon centers with C (sp 3)–C (sp 3) bonds are subunits extensively occur in
natural products, bioactive targets, and chiral organic materials. Transition-metal-catalyzed …

Catalytic branch-selective hydrofunctionalization of feedstock α-olefins to form
enantioenriched chiral compounds is a particularly attractive yet challenging transformation …

Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely
utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric …

Conspectus Alkenes are versatile compounds that are readily available on a large scale
from industry or through organic synthesis. The widespread occurrence of alkenes provides …

In recent years, metal-catalysed asymmetric sequential double hydrofunctionalization of
alkynes (ASDHA) has emerged as a powerful strategy to construct valuable chiral products …

Hydrofunctionalization of alkenes and alkynes is increasingly important in preparing and
modifying carbon-centered organic molecules such as pharmaceuticals, agrochemicals, and …

Direct construction of fully alkyl-substituted tertiary chiral centers remote to activating groups
is highly challenging and desirable. Herein, a Ni-catalyzed enantioselective hydroalkylation …

Catalytic enantioselective synthesis of small-molecule building blocks with allylic
stereogenic centers is an important objective in organic synthesis, but preparing this motif …