Dearomative spirocyclization reactions represent a promising means to convert arenes into
three‐dimensional architectures; however, controlling the regioselectivity of radical …

Aromatic compounds are one of the most abundant classes of organic molecules and find
utility as precursors for alicyclic hydrocarbon building blocks. While many established …

Dearomatization approaches are attractive for their abilities to transform simple, planar
arenes into complex, three-dimensional architectures. In particular, visible-light driven …

A dearomative reduction of simple arenes has been developed which employs a visible‐
light‐mediated cycloaddition of arenes with an N‐N‐arenophile and in situ diimide …

An unprecedented base-promoted multi-component one-pot dearomatization of N-alkyl
activated azaarenes was developed, which enabled the synthesis of complex and diverse …

A photocatalytic protocol for the divergent dearomative functionalization of indole derivatives
is reported. Under the irradiation of visible light, either dimerization or reduction occurs …

Dearomatization reactions employing simple aromatic compounds have showcased
remarkable progress in the recent decade and have emerged as one of the most …

Dearomatisation reactions of (hetero) arenes have been widely employed as efficient
methods to obtain highly substituted saturated cyclic compounds for over a century. In recent …

The cleavage of an unactivated aryl nitro group triggered by alkyl radicals enables a
dearomative cyclization, affording diversified alkylated spiro [5.5] trienones in good yields …

Herein, we report a protocol for visible-light-induced dearomative oxamination reactions of
indole derivatives to afford functionalized spirocyclic products. These step-economical …