Microwave Irradiation for the Facile Synthesis of Transition‐Metal Nanoparticles (NPs) in Ionic Liquids (ILs) from Metal–Carbonyl Precursors and Ru‐, Rh‐, and Ir‐NP …

C Vollmer, E Redel, K Abu‐Shandi… - … A European Journal, 2010 - Wiley Online Library
Stable chromium, molybdenum, tungsten, manganese, rhenium, ruthenium, osmium, cobalt,
rhodium, and iridium metal nanoparticles (M‐NPs) have been reproducibly obtained by …

Synthesis of Co, Rh and Ir nanoparticles from metal carbonyls in ionic liquids and their use as biphasic liquid–liquid hydrogenation nanocatalysts for cyclohexene

E Redel, J Krämer, R Thomann, C Janiak - Journal of Organometallic …, 2009 - Elsevier
Stable cobalt, rhodium and iridium nanoparticles are obtained reproducibly by thermal
decomposition under argon from Co2 (CO) 8, Rh6 (CO) 16 and Ir4 (CO) 12 dissolved in the …

The use of microwave irradiation for the easy synthesis of graphene-supported transition metal nanoparticles in ionic liquids

D Marquardt, C Vollmer, R Thomann, P Steurer… - Carbon, 2011 - Elsevier
Stable ruthenium or rhodium metal nanoparticles were supported on chemically derived
graphene (CDG) surfaces with small and uniform particle sizes (Ru 2.2±0.4 nm and Rh …

The partial hydrogenation of benzene to cyclohexene by nanoscale ruthenium catalysts in imidazolium ionic liquids

ET Silveira, AP Umpierre, LM Rossi… - … A European Journal, 2004 - Wiley Online Library
The controlled decomposition of an Ru0 organometallic precursor dispersed in 1‐n‐butyl‐3‐
methylimidazolium hexafluorophosphate (BMI⋅ PF6), tetrafluoroborate (BMI⋅ BF4) or …

Olefin hydrogenation by ruthenium nanoparticles in ionic liquid media: Does size matter?

PS Campbell, CC Santini, F Bayard, Y Chauvin… - Journal of …, 2010 - Elsevier
Tailor-made and size-controlled ruthenium nanoparticles, RuNPs, of three distinct sizes
between 1 and 3nm are generated from the decomposition of (η4-1, 5-cyclooctadiene)(η6-1 …

Ruthenium nanoparticle catalysts stabilized in phosphonium and imidazolium ionic liquids: dependence of catalyst stability and activity on the ionicity of the ionic …

KL Luska, A Moores - Green Chemistry, 2012 - pubs.rsc.org
Ruthenium nanoparticles (Ru NPs) were synthesized from the reduction of Ru (2-
methylallyl) 2 (cod) under an atmosphere of H2 (g) in a series of phosphonium and …

Ionic liquids for the synthesis and stabilization of metal nanoparticles

C Janiak - Zeitschrift für Naturforschung B, 2013 - degruyter.com
The synthesis and stabilization of metal nanoparticles (M-NPs) from metals, metal salts,
metal complexes and metal carbonyls in ionic liquids (ILs) is reviewed. The electrostatic and …

Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (CoxRh100−x@SILP) as Catalysts for the Selective …

S Rengshausen, C Van Stappen, N Levin, S Tricard… - Small, 2021 - Wiley Online Library
The synthesis, characterization, and catalytic properties of bimetallic cobalt‐rhodium
nanoparticles of defined Co: Rh ratios immobilized in an imidazolium‐based supported ionic …

Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids: II. Rhodium-catalyzed hydrogenation of arenes

C Zhao, H Wang, N Yan, C Xiao, X Mu, PJ Dyson… - Journal of …, 2007 - Elsevier
Rhodium nanoparticles stabilized by the ionic-liquid-like copolymer poly [(N-vinyl-2-
pyrrolidone)-co-(1-vinyl-3-butylimidazolium chloride)] were used to catalyze the …

Preparation of rhodium nanoparticles in carbon dioxide induced ionic liquids and their application to selective hydrogenation

V Cimpeanu, M Kočevar, VI Parvulescu… - Angewandte …, 2009 - Wiley Online Library
There is currently great interest in the generation of metal nanoparticles of controlled size
and shape because of their unique properties at the interface between molecular structures …