Dearomatization and direct C (sp3)–H functionalization represent two hot research fields in
organic synthesis, the merging of which is among the most challenging but appealing topics …

Direct functionalization of C (sp3)–H bonds represents a pivotal objective in the realm of
synthetic chemistry. However, inherent chemical inertness coupled with low reactivity …

Hydride transfer enabled the first success of the regioselective dearomatization of indoles in
the carbocyclic ring and the pyrrole ring, which was induced by ortho-quinone methides and …

The redox-neutral cascade dearomatization of indoles with o-aminobenzaldehydes has
been realized via the hydride transfer strategy, achieving the condition-and substrate …

The hydride transfer reaction, which is characterized by a redox-neutral and step/atom
economic process, has emerged as an enabling platform for C (sp3)–H activation with high …

Abstract The α-C (sp 3)–H functionalization of ethers via cascade [1, n]-hydride
transfer/cyclization, which features redox-neutral nature, atom-economy, and high efficiency …

Hydride shift mediated C (sp 3)–H bond functionalization, namely, internal redox reaction, is
an useful synthetic tool for the construction of fused cycles. Most of the reactions reported so …

Carbon-hydrogen (C− H) functionalization of pyridines is a powerful tool for the rapid
construction and derivatization of many agrochemicals, pharmaceuticals, and materials …

An unprecedented cascade dearomative cyclization through hydrogen-bonding-assisted
hydride transfer is realized. The aggregate effect of HFIP enables the rapid buildup of …

The remote C (sp3)–H functionalization enabled by a radical-mediated 1, 5-hydrogen-atom
transfer (HAT) process using vinyl azides and 1, 4-dihydropyridines as precursors has been …